TY  - JOUR
A1  - Wanczek, Karl-Peter
A1  - Lebert, Karl-Heinz
A1  - Hartmann, Hermann
T1  - Untersuchung der Ion-Molekül-Reaktionen des Thiothionylfluorids mit Hilfe der Ionen-Cyclotronresonanz-Spektrometrie
T1  - Investigation Of Ion-Molecule Reactions Of Thiothionylfluorid By Ion Cyclotron Resonance Spectrometry
T2  - Zeitschrift für Naturforschung, A
N2  - The ion-molecule reactions of thiothionylfluoride have been studied by ion cyclotron resonance spectrometry. The major secondary ions are S2F3+ , S3F+ , and S3F2+. In a consecutive reaction of S3F2+ the tertiary ion S4F2+ is formed. The rate constant of the IMR with the greatest yield S2F2+ + SSF2 → S3F2+ + SF was estimated to k = 2 · 10-9 cm 3 molecule -1 sec -1 . The results were compared with the mass spectrum of thiothionylfluoride. They permit conclusions on chemical reactions of lower sulphurfluorides.
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/74039
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-740395
SN  - 1865-7109
VL  - 27
IS  - 1
SP  - 155
EP  - 158
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -