TY  - JOUR
A1  - Schmidt, Reinhard
A1  - Brauer, Hans-Dieter
T1  - Über das Assoziationsverhalten des Schlenkschen Kohlenwasserstoffs
T1  - About the association of Schlenk’s hydrocarbon
T2  - Zeitschrift für Naturforschung, B
N2  - The association of Schlen k’s hydrocarbon was studied by means of osmometric and magnetic measurements. The mixed chain-ring-association can be explained satisfactorily assuming that two different dimers and four monomer species participate in the equilibria, including a monomeric diamagnetic ring. The equilibria existing between the different species are discussed. For the equilibria between the monomer and dimer species, which can be detected in solutions of normal viscosity by means of ESR-measurements, the unexpected values of ΔH=0 for the enthalpie of association and ΔS= +19.7 e. u. for the entropie of association were found.
Y1  - 2014
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/76111
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-761118
SN  - 1865-7117
SN  - 0932-0776
VL  - 27
IS  - 11
SP  - 1363
EP  - 1370
PB  - Verlag der Zeitschrift für Naturforschung
CY  - Tübingen
ER  -