TY  - JOUR
A1  - Essehli, Rachid
A1  - El Bali, Brahim
A1  - Lachkar, Mohammed
A1  - Bolte, Michael
T1  - Dicaesium magnesium bis(dihydrogen phosphate(V)) dihydrate
T2  - Acta crystallographica / Section E, Structure reports online
N2  - The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs+ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg2+ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(P–O) = 0.006 Å; R factor = 0.048; wR factor = 0.125; data-to-parameter ratio = 12.3.
Y1  - 2009
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/6939
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30-69529
N1  - This is an open-access article distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
VL  - 65
IS  - i3
ER  -