TY  - JOUR
A1  - Rivera, Augusto
A1  - Uribe, Juan Manuel
A1  - Rojas, Jicli José
A1  - Ríos-Motta, Jaime
A1  - Bolte, Michael
T1  - Crystal structure of the co-crystalline adduct 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]do­decane (TATD)–4-bromo­phenol (1/2)
T2  - Acta crystallographica. Section E, Crystallographic communications
N2  - The structure of the 1:2 co-crystalline adduct C8H16N4·2C6H5BrO, (I), from the solid-state reaction of 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]dodecane (TATD) and 4-bromo­phenol, has been determined. The asymmetric unit of the title co-crystalline adduct comprises a half mol­ecule of aminal cage polyamine plus a 4-bromo­phenol mol­ecule. A twofold rotation axis generates the other half of the adduct. The primary inter-species association in the title compound is through two inter­molecular O—H⋯N hydrogen bonds. In the crystal, the adducts are linked by weak non-conventional C—H⋯O and C—H⋯Br hydrogen bonds, giving a two-dimensional supra­molecular structure parallel to the bc plane.
KW  - crystal structure
KW  - co-crystalline adducts
KW  - TATD
KW  - proton transfer
KW  - hydrogen bonding
Y1  - 2015
UR  - http://publikationen.ub.uni-frankfurt.de/frontdoor/index/index/docId/39233
UR  - https://nbn-resolving.org/urn:nbn:de:hebis:30:3-392335
SN  - 2056-9890
N1  - This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode , which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
VL  - 71
SP  - 463
EP  - 465
PB  - International Union of Crystallography
CY  - Chester
ER  -