(Biphenyl-2-yl)bromidobis(2-methyltetrahydrofuran-[kappa]O)magnesium(II)

In the title Grignard reagent, [MgBr(C12H9)(C5H10O)2], the Mg centre adopts a distorted tetrahedral MgCO2Br arrangement. The dihedral angle between the two aromatic rings of the biphenyl residue is 44.00 (14)°. Each molecule incorporates one R- and one S-configured 2-methyltetrahydrofuran molecule. Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.007 Å; R factor = 0.045; wR factor = 0.108; data-to-parameter ratio = 17.4.

Metadaten
Author:	Simon Nordschild, David Wohlgemuth, Michael Bolte ORCiD
URN:	urn:nbn:de:hebis:30-69483
DOI:	https://doi.org/10.1107/S1600536809012185
Parent Title (English):	Acta crystallographica / Section E, Structure reports online
Document Type:	Article
Language:	English
Year of Completion:	2009
Year of first Publication:	2009
Publishing Institution:	Universitätsbibliothek Johann Christian Senckenberg
Release Date:	2009/09/09
Volume:	65
Issue:	m493
Note:	This is an open-access article distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:	Acta Crystallographica Section E, Structure Reports Online, 2009, E65, m493 ; doi:10.1107/S1600536809012185
HeBIS-PPN:	217663311
Institutes:	Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):	Creative Commons - Namensnennung 2.0

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