N-(3-Nitrobenzylidene)aniline

  • In the title compound, C13H10N2O2, a Schiff base derivative, the dihedral angle between the two aromatic rings is 31.58 (3)°. The C=N double bond is essentially coplanar with the nitrophenyl ring. The torsion angle of the imine double bond is 175.97 (13)°, indicating that the C=N double bond is in a trans configuration. The crystal structure is stabilized by C-H...O contacts and [pi]-[pi] interactions (centroid-centroid distances of 3.807 and 3.808 Å). Key indicators: single-crystal X-ray study; T = 173 K; mean σ(C–C) = 0.002 Å; R factor = 0.034; wR factor = 0.093; data-to-parameter ratio = 10.3.

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Metadaten
Author:Muhammad Zaheer, Zareen Akhter, Michael BolteORCiD, Humaira Masood Siddiqi
URN:urn:nbn:de:hebis:30-69444
DOI:https://doi.org/10.1107/S1600536808036970
Parent Title (English):Acta crystallographica / Section E, Structure reports online
Document Type:Article
Language:English
Year of Completion:2008
Year of first Publication:2008
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2009/09/08
Volume:64
Issue:o2381–o2382
Note:
This is an open-access article distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Source:Acta Crystallographica Section E, Structure Reports Online, 2008, E64, o2381–o2382 ; doi:10.1107/S1600536808036970
HeBIS-PPN:217653251
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Licence (German):License LogoCreative Commons - Namensnennung 2.0