Di-μ-bromido-bis-[(diethyl ether-κO)(2,4,6-trimethylphenyl)magnesium] : the mesityl Grignard reagent
- The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric two-centre magnesium complex with half a mol-ecule in the asymmetric unit. The Mg atom is in a considerably distorted Br2CO coordination. Bond lengths and angles are comparable with already published values. The crystal packing is stabilized by C-H⋯π inter-actions linking the complexes into sheets parallel to (0-11).
| Author: | Ömer Seven, Michael BolteORCiD, Hans-Wolfram LernerORCiDGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-318074 |
| DOI: | https://doi.org/10.1107/S1600536813017108 |
| ISSN: | 1600-5368 |
| Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/24046588 |
| Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2013/06/29 |
| Date of first Publication: | 2013/06/29 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2013/10/15 |
| Volume: | 69 |
| Page Number: | 12 |
| First Page: | m424 |
| Last Page: | m424 |
| Note: | Copyright © Seven et al. 2013 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| HeBIS-PPN: | 36278034X |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 3.0 |
