Gavin J. Phillips, Jim Thieser, Mingjin Tang, Nicolas Sobanski, Gerhard Schuster, Johannes Fachinger, Frank Drewnick, Stephan Borrmann, Heinz Bingemer, Jos Lelieveld, John N. Crowley
- We present an estimation of the uptake coefficient (γ) and yield of nitryl chloride (ClNO2) (f) for the heterogeneous processing of dinitrogen pentoxide (N2O5) using simultaneous measurements of particle and trace gas composition at a semi-rural, non-coastal, mountain site in the summer of 2011. The yield of ClNO2 varied between (0.035 ± 0.027) and (1.38 ± 0.60) with a campaign average of (0.49 ± 0.35). The large variability in f reflects the highly variable chloride content of particles at the site. Uptake coefficients were also highly variable with minimum, maximum and average γ values of 0.004, 0.11 and 0.028 ± 0.029, respectively, with no significant correlation with particle composition, but a weak dependence on relative humidity. The uptake coefficients obtained are compared to existing parameterizations based on laboratory datasets and with other values obtained by analysis of field data.
Metadaten| Author: | Gavin J. Phillips, Jim Thieser, Mingjin Tang, Nicolas Sobanski, Gerhard Schuster, Johannes Fachinger, Frank Drewnick, Stephan BorrmannORCiDGND, Heinz BingemerGND, Jos LelieveldORCiDGND, John N. Crowley |
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| URN: | urn:nbn:de:hebis:30:3-420117 |
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| URL: | http://www.atmos-chem-phys.net/16/13231/2016 |
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| DOI: | https://doi.org/10.5194/acp-16-13231-2016 |
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| ISSN: | 1680-7324 |
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| ISSN: | 1680-7316 |
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| Parent Title (English): | Atmospheric chemistry and physics |
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| Publisher: | European Geosciences Union |
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| Place of publication: | Katlenburg-Lindau |
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| Contributor(s): | T. Bertram |
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| Document Type: | Article |
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| Language: | English |
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| Date of Publication (online): | 2016/11/14 |
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| Date of first Publication: | 2016/10/27 |
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| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
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| Release Date: | 2016/11/14 |
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| Volume: | 16 |
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| Issue: | 20 |
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| Page Number: | 19 |
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| First Page: | 13231 |
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| Last Page: | 13249 |
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| Note: | © Author(s) 2016. CC Attribution 3.0 License. |
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| HeBIS-PPN: | 42400559X |
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| Institutes: | Geowissenschaften / Geographie / Geowissenschaften |
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| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften |
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| Sammlungen: | Universitätspublikationen |
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| Licence (German): |  Creative Commons - Namensnennung 3.0 |
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Creative Commons - Namensnennung 3.0