Crystal structure of 1,3-bis[(E)-4-methoxybenzylideneamino]propan-2-ol
- The title Schiff base, C19H22N2O3, was synthesized via the condensation reaction of 1,3-diaminopropan-2-ol with 4-methoxybenzaldehyde using water as solvent. The molecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O-H...N hydrogen bonds link the molecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C-H...O interactions and C-H...[pi] short contacts, forming a three-dimensional network.
Download full text files
Additional Services
| Author: | Augusto RiveraORCiD, Ingrid Johanna Miranda CarvajalORCiD, Jaime Ríos-MottaORCiD, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-428952 |
| URL: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137596 |
| DOI: | https://doi.org/10.1107/S2056989016016947 |
| ISSN: | 2056-9890 |
| Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/27980818 |
| Parent Title (English): | Acta crystallographica. Section E, Crystallographic communications |
| Publisher: | International Union of Crystallography |
| Place of publication: | Chester |
| Contributor(s): | W. T. A. Harrison |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2017/02/23 |
| Date of first Publication: | 2016/10/22 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2017/02/23 |
| Tag: | C-H...O interactions; Schiff bases; crystal structure; hydrogen bonding |
| Volume: | 72 |
| Issue: | Pt 12 |
| Page Number: | 8 |
| First Page: | 1731 |
| Last Page: | 1733 |
| Note: | This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| HeBIS-PPN: | 450967670 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 2.0 |
