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The Southeast Asian scarab beetle genus Peltonotus Burmeister (Scarabaeidae: Dynastinae) is associated with aroid flowers and possesses a unique, articulated maxillary tooth. We describe five new species of Peltonotus: P. animus and P. cybele from Sumatra, P. favonius from Vietnam, P. mushiyaus from Borneo, and P. tigerus from Thailand. The circumscription of P. karubei Muramoto is broadened to include new color variation, and the body size range for the genus is increased with Peltonotus mushiyaus, n. sp., now being the smallest member of the genus. We provide an amended key to species, distribution maps, diagnoses and accompanying comparative images, and discuss classification of the genus within the Scarabaeidae.
Real-time observation of X-ray-induced intramolecular and interatomic electronic decay in CH2I2
(2019)
The increasing availability of X-ray free-electron lasers (XFELs) has catalyzed the development of single-object structural determination and of structural dynamics tracking in real-time. Disentangling the molecular-level reactions triggered by the interaction with an XFEL pulse is a fundamental step towards developing such applications. Here we report real-time observations of XFEL-induced electronic decay via short-lived transient electronic states in the diiodomethane molecule, using a femtosecond near-infrared probe laser. We determine the lifetimes of the transient states populated during the XFEL-induced Auger cascades and find that multiply charged iodine ions are issued from short-lived (∼20 fs) transient states, whereas the singly charged ones originate from significantly longer-lived states (∼100 fs). We identify the mechanisms behind these different time scales: contrary to the short-lived transient states which relax by molecular Auger decay, the long-lived ones decay by an interatomic Coulombic decay between two iodine atoms, during the molecular fragmentation.
