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Sulfur in the slab: a sulfur-isotopes and thermodynamic-modeling perspective from exhumed terranes
(2022)
Sulfur is a key element in the subduction zone-volcanic arc system; however, the mechanism(s) that recycle sulfur from the slab into the overlying volcanic arc are debated. Here we summarize recent advances in quantifying this component of the deep sulfur cycle. First, primary metamorphic or inherited sulfides in oceanic-type eclogites are only rarely observed as inclusions and are typically absent from the rock matrix. Additionally, sulfides are relatively common in rocks metasomatized at the slab-mantle interface by slab-derived fluids during exhumation. Combined, these two observations suggest that sulfur loss from subducted mafic crust is relatively efficient. Thermodynamic modeling in Perple_X using the Holland and Powell (2011) database combined with the Deep Earth Water model suggests that the efficiency and speciation of sulfur loss varies depending on the degree of seafloor alteration prior to subduction and the geothermal gradient of the slab. In relatively cold subduction zones, such as Honshu, slab-fluids derived from subducted mafic crust are predicted to exhibit elevated concentrations of HSO4-, SO42-, HSO3-, and CaSO4(aq), whereas hot subduction zones, such as Cascadia, are predicted to produce slab fluids enriched in HS- and H2S at lower pressures. The oxidation of sulfur expelled from subducted pyrite is balanced by the reduction of Fe3+ to Fe2+, consistent with the low Fe3+/SFe of exhumed eclogites relative to blueschists and altered oceanic crust. Where oxidized S-bearing fluids are produced, they are anticipated to interact with more reduced rocks at the slab-mantle interface and within the mantle wedge, resulting in sulfide precipitation and significant isotopic fractionation. The δ34S values of slab fluids are estimated to fall between -11 and +8 ‰. Rayleigh fractionation during progressive fluid-rock interaction results in fractionations of tens of per mil as oxidized species are depleted and sulfides are precipitated, resulting in δ34S values of sulfides that easily span the -21.7 to +13.9 ‰ range observed in metasomatic sulfides in exhumed high-pressure rocks. However, in subduction zones where reduced species prevail, the S isotopic signature of slab fluids is expected to reflect their source and will exhibit a narrower range in δ34S values. As a result, the δ34S values measured in arc magmas may not always be a reliable indicator of the contribution of different components of the slab, such as sediments vs. AOC. Additionally, the impact of S recycling on the oxygen fugacity of arc magmas is expected to vary both spatially and temporally throughout Earth history.
We compute the equation of state of isospin asymmetric QCD at zero and non-zero temperatures using direct simulations of lattice QCD with three dynamical flavors at physical quark masses. In addition to the pressure and the trace anomaly and their behavior towards the continuum limit, we will particularly discuss the extraction of the speed of sound. Furthermore, we discuss first steps towards the extension of the EoS to small non-zero baryon chemical potentials via Taylor expansion.
The interrelation between quantum anomalies and electromagnetic fields leads to a series of non-dissipative transport effects in QCD. In this work we study anomalous transport phenomena with lattice QCD simulations using improved staggered quarks in the presence of a background magnetic field. In particular, we calculate the conductivities both in the free case and in the interacting case, analysing the dependence of these coefficients with several parameters, such as the temperature and the quark mass.
We discuss results for the Roberge Weiss (RW) phase transition at nonzero imaginary baryon and isospin chemical potentials, in the plane of temperature and quark masses. Our study focuses on the light tricritical endpoint which has already been used as a starting point for extrapolations aiming at the chiral limit at vanishing chemical potentials. In particular, we are interested in determining how imaginary isospin chemical potential shifts the tricritical mass with respect to earlier studies at zero imaginary isospin chemical potential. A positive shift might allow one to perform the chiral extrapolations from larger quark mass values, therefore making them less computationally expensive. We also present results for the dynamics of Polyakov loop clusters across the RW phase transition.
In this work, the phase diagram of the 2+1-dimensional Gross-Neveu model is investigated with baryon chemical potential as well as chiral chemical potential in the mean-field approximation. We study the theory using two lattice discretizations, which are both based on naive fermions. An inhomogeneous chiral phase is observed only for one of the two discretizations. Our results suggest that this phase disappears in the continuum limit.
Nitrogen pollution is a major constituent of global change, threatening local biodiversity, ecosystem services, and causing serious environmental damage. Specifically, in areas with heavy agricultural soil-use, excessive use of nitrogen fertilizer pollutes the groundwaters with nitrates, but also with ammonia and nitrites. Freshwater fish and other aquatic fauna are especially vulnerable to nitrites, which can cause massive mortalities at even low concentrations < 0.1 mg/l NO2- - N. Adaptation of fish to environments with relatively high concentrations of chemicals has occurred throughout the history of life, although contemporary evolution acts at a much more rapid pace. The growing use of land for mass agriculture and livestock industries in the last 50 years in Florida has dramatically increased the nutrient loading into the groundwaters that feed the springs. Nitrite poses a serious threat for freshwater fauna as it is rapidly up taken and disturbs ion homeostasis and blood gas transport in fish. In this study, we evaluated, by means of a common-garden experiment, the tolerance of fish to nitrite using three different populations of eastern mosquitofish (Gambusia holbrooki) with different background nitrogen pollution histories. Mosquitofish females were exposed to nitrite in the lab, to either < 0.005 mg/l NO2- (control) or 0.3 mg/l NO2- for ten days and we assessed at the end of the exposure period their blood O2 transport capacity by measuring the concentration of four different types of hemoglobin, their total hematocrit, and their respiratory rates. Preliminary results show slight but significant varying patterns in the response of the exposed fish, depending on the population source, as evidenced by their respiratory rates and the blood erythrocyte counts. Mortality was very low, and hemoglobin profiles indicate high tolerance of G. holbrooki to nitrite contamination – a factor supporting their invasion success in agriculturally dominated regions around the world.
Differential invariant cross sections of light neutral mesons in p-Pb collisions at √sNN = 8.16 TeV and in pp collisions at √s = 8 TeV have been measured up to very high transverse momentum (pT). By combining independent reconstruction techniques available in ALICE using the EMCal and PHOS calorimeters as well as the central barrel tracking detectors, the combined spectra cover almost two orders of magnitude in pT for the π0 meson. The nuclear modification factor RpPb has been measured for the π0 and η mesons and is found to be consistent with NLO pQCD, CGC and energy loss calculations. Comparisons to the RpPb of π0 measured in √sNN = 5.02 TeV hint at a stronger suppression at low pT with increasing collision energy.