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The relative stability of the siliconbromidechlorides is discussed on the timedependence of the dismutation reaction of SiCl3Br, on the measured appearence potentials of SiCl3, from SiCl3Br and SiCl4 respectively and on the enthalpies of the hydrolysis reactions. The relative strengths of the Si-Br-bonds of the different compounds were estimated, using SiCl4 as a standard.
The ion-molecule reactions of thiothionylfluoride have been studied by ion cyclotron resonance spectrometry. The major secondary ions are S2F3+ , S3F+ , and S3F2+. In a consecutive reaction of S3F2+ the tertiary ion S4F2+ is formed. The rate constant of the IMR with the greatest yield S2F2+ + SSF2 → S3F2+ + SF was estimated to k = 2 · 10-9 cm 3 molecule -1 sec -1 . The results were compared with the mass spectrum of thiothionylfluoride. They permit conclusions on chemical reactions of lower sulphurfluorides.