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Mikrowellenspektrum und Struktur von Tribromsilan

  • The microwave spectra of SiHBr3 and SiDBr3 have been investigated in the region from 28 to 40 GHz. From the rotational constants the following structural parameters were derived by a least square method: dSi-H = (1,494 ± 0,009) A, dSi-Br = (2,170 ± 0,001) Å, ∢Br-Si-Br = (111,36 ± 0,25)0. The results are compared with those obtained for other Si-halogen-compounds.

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Metadaten
Author:Michael MitzlaffGND, Reimer Holm, Hermann HartmannGND
URN:urn:nbn:de:hebis:30:3-740776
DOI:https://doi.org/10.1515/zna-1968-0111
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1968
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/06/23
Volume:23
Issue:1
Page Number:3
First Page:65
Last Page:67
HeBIS-PPN:510491391
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0