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Fluctuation theory of irreversible processes

  • LANGEVIN equations of the type dn× (t)/dtn+...+c × (t)=K (t) constitute the starting point of a phenomenological fluctuation theory of irreversible processes. These equations are not constructed from transport equations (as in the older theory), but via a generalized MASTER equation from phase space mechanics. The MARKOFF processes of first and higher order defined by the various LANGEVIN equations are studied by the prediction theory of stationary stochastic processes. Instead of the variation principle of the ONSAGEB–MACHLUP theory one has the minimization of the prediction error. The mean relaxation path and the entropy of the considered processes are calculated. It is shown that the entropy consists of one part which is given by the relaxation path and another which is determined by the prediction error.

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Metadaten
Author:Christoph SchneeweißGND
URN:urn:nbn:de:hebis:30:3-740810
DOI:https://doi.org/10.1515/zna-1967-1102
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:English
Date of Publication (online):2014/06/02
Year of first Publication:1967
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/06/26
Volume:22
Issue:11
Page Number:7
First Page:1671
Last Page:1677
HeBIS-PPN:510501605
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0