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Abelev, Betty ; Adam, Jaroslav ; Adamová, Dagmar ; Aggarwal, Madan Mohan ; Aglieri Rinella, Gianluca ; Agnello, Michelangelo ; Agocs, Andras Gabor ; Agostinelli, A. ; Agrawal, Neelima ; Ahammed, Zubayer ; Ahmad, Nazeer ; Ahmad Masoodi, A. ; Ahmed, I. ; Ahn, Sang Un ; Ahn, S. A. ; Aimo, Ilaria ; Aiola, Salvatore ; Ajaz, Muhammad ; Akindinov, Alexander ; Aleksandrov, Dmitry ; Alessandro, Bruno ; Alexandre, Didier ; Alici, Andrea ; Alkin, Anton ; Alme, Johan ; Alt, Torsten ; Altini, Valerio ; Altinpinar, Sedat ; Altsybeev, Igor ; Prado, Caio Alves Garcia ; Andrei, Cristian ; Andronic, Anton ; Anguelov, Venelin ; Anielski, Jonas ; Antičić, Tome ; Antinori, Federico ; Antonioli, Pietro ; Aphecetche, Laurent Bernard ; Appelshäuser, Harald ; Arbor, N. ; Arcelli, Silvia ; Armesto, Néstor ; Arnaldi, Roberta ; Aronsson, Tomas Robert ; Arsene, Ionut Cristian ; Arslandok, Mesut ; Augustinus, Andre ; Averbeck, Ralf Peter ; Awes, Terry C. ; Azmi, Mohd Danish ; Bach, Matthias ; Badalà, Angela ; Baek, Yong Wook ; Bagnasco, Stefano ; Bailhache, Raphaëlle ; Bairathi, Vipul ; Bala, Renu ; Baldisseri, Alberto ; Baltasar Dos Santos Pedrosa, Fernando ; Bán, J. ; Baral, Rama Chandra ; Barbera, Roberto ; Barile, Francesco ; Barnaföldi, Gergely Gábor ; Barnby, Lee Stuart ; Barret, Valerie ; Bartke, Jerzy ; Basile, Maurizio ; Bastid, Nicole ; Basu, Sumit ; Bathen, Bastian ; Batigne, Guillaume ; Batyunya, Boris ; Bätzing, Paul Christoph ; Baumann, C. ; Bearden, Ian Gardner ; Beck, Hans ; Bedda, Cristina ; Behera, Nirbhay Kumar ; Belikov, Iouri ; Bellini, Francesca ; Bellwied, Rene ; Belmont-Moreno, Ernesto ; Bencédi, Gyula ; Beolè, Stefania ; Berceanu, Ionela ; Barnaföldi, Gergely Gábor ; Barnby, Lee Stuart ; Barret, Valerie ; Bartke, Jerzy ; Basile, Maurizio ; Bastid, Nicole ; Basu, Sumit ; Bathen, Bastian ; Batigne, Guillaume ; Batyunya, Boris ; Bätzing, Paul Christoph ; Baumann, C. ; Bearden, Ian Gardner ; Beck, Hans ; Bedda, Cristina ; Behera, Nirbhay Kumar ; Belikov, Iouri ; Bellini, Francesca ; Bellwied, Rene ; Belmont-Moreno, Ernesto ; Bencédi, Gyula ; Beolè, Stefania ; Berceanu, Ionela ; Bogolyubsky, M. ; Boldizsár, László ; Bombara, Marek ; Book, Julian ; Borel, Hervé ; Borissov, Alexander ; Bornschein, Jörg ; Bossú, Francesco ; Botje, Michiel ; Botta, Elena ; Böttger, Stefan ; Braun-Munzinger, Peter ; Bregant, Marco ; Breitner, Timo ; Broker, Theo Alexander ; Browning, Tyler Allen ; Broz, Michal ; Bruna, Elena ; Bruno, Giuseppe Eugenio ; Budnikov, Dmitry ; Büsching, Henner ; Bufalino, Stefania ; Bunčić, Predrag ; Busch, Oliver ; Buthelezi, Edith Zinhle ; Caffarri, Davide ; Cai, Xiao ; Caines, Helen Louise ; Caliva, Alberto ; Calvo Villar, Ernesto ; Camerini, Paolo ; Canoa Roman, V. ; Carena, Francesco ; Carena, Wisla ; Carminati, Federico ; Casanova Díaz, Amaya Ofelia ; Castillo Castellanos, Javier Ernesto ; Casula, Ester Anna Rita ; Catanescu, V. ; Cavicchioli, Costanza ; Ceballos Sanchez, Cesar ; Čepila, Jan ; Cerello, Piergiorgio ; Chang, Beom-Su ; Chapeland, Sylvain ; Charvet, Jean-Luc Fernand ; Chattopadhyay, Subhasis ; Chattopadhyay, Sukalyan ; Cherney, Michael Gerard ; Cheshkov, Cvetan Valeriev ; Cheynis, Brigitte ; Chibante Barroso, Vasco Miguel ; Chinellato, David Dobrigkeit ; Chochula, Peter ; Chojnacki, Marek ; Choudhury, Subikash ; Christakoglou, Panagiotis ; Christensen, Christian Holm ; Christiansen, Peter L. ; Chujo, Tatsuya ; Chung, Suh-Urk ; Cicalò, Corrado ; Cifarelli, Luisa ; Cindolo, Federico ; Cleymans, Jean Willy Andre ; Colamaria, Fabio Filippo ; Colella, Domenico ; Collu, Alberto ; Colocci, Manuel ; Conesa Balbastre, Gustavo ; Conesa del Valle, Zaida ; Connors, Megan Elizabeth ; Contin, Giacomo ; Contreras Nuno, Jesus Guillermo ; Cormier, Thomas Michael ; Corrales Morales, Yasser ; Cortese, Pietro ; Cortés Maldonado, Ismael ; Cosentino, Mauro Rogerio ; Costa, Filippo ; Crochet, Philippe ; Cruz Albino, Rigoberto ; Cuautle Flores, Eleazar ; Cunqueiro Mendez, Leticia ; Dainese, Andrea ; Dang, R. ; Danu, Andrea ; Das, Debasish ; Das, Indranil ; Das, K. ; Das, S. ; Dash, Ajay Kumar ; Dash, Sadhana ; De, Sudipan ; Delagrange, H. ; Deloff, Andrzej ; Dénes, Ervin Sandor ; D’Erasmo, Ginevra ; Barros, Gabriel Oliveira Valeriano de ; De Caro, Annalisa ; De Cataldo, Giacinto ; Cuveland, Jan de ; De Falco, Alessandro ; De Gruttola, Daniele ; De Marco, Nora ; De Pasquale, Salvatore ; de Rooij, R. ; Diaz Corchero, Miguel Angel ; Dietel, Thomas ; Divià, Roberto ; Di Bari, Domenico ; Di Liberto, S. ; Di Mauro, Antonio ; Di Nezza, Pasquale ; Djuvsland, Øystein ; Dobrin, Alexandru Florin ; Dobrowolski, Tadeusz Antoni ; Domenicis Gimenez, Diogenes ; Dönigus, Benjamin ; Dordic, Olja ; Dorheim, Sverre ; Dubey, Anand Kumar ; Dubla, Andrea ; Ducroux, Laurent ; Dupieux, Pascal ; Dutta Majumdar, Abhee Kanti ; Elia, Domenico ; Engel, Heiko ; Erazmus, Barbara Ewa ; Erdal, H. A. ; Eschweiler, Dominic ; Espagnon, Bruno ; Estienne, Magali Danielle ; Esumi, ShinIchi ; Evans, David ; Evdokimov, Sergey ; Eyyubova, Gyulnara ; Fabris, Daniela ; Faivre, Julien ; Falchieri, D. ; Fantoni, Alessandra ; Fasel, Markus ; Fehlker, D. ; Feldkamp, Linus ; Felea, Daniel ; Feliciello, Alessandro ; Feofilov, Grigori A. ; Ferencei, Jozef ; Fernández Téllez, Arturo ; Gonzalez Ferreiro, Elena ; Ferretti, Alessandro ; Festanti, Andrea ; Figiel, Jan ; Figueredo, Marcel Araujo Silva ; Filchagin, Sergey ; Finogeev, Dmitry ; Fionda, Fiorella Maria Celeste ; Fiore, Enrichetta Maria ; Floratos, E. ; Floris, Michele ; Foertsch, Siegfried Valentin ; Foka, Panagiota ; Fokin, Sergey ; Fragiacomo, Enrico ; Francescon, Andrea ; Frankenfeld, Ulrich ; Fuchs, Ulrich ; Furget, Christophe ; Fusco Girard, Mario ; Gaardhøje, Jens Jørgen ; Gagliardi, Martino ; Gallio, Mauro ; Gangadharan, Dhevan Raja ; Ganoti, Paraskevi ; Garabatos, Chilo ; Garcia-Solis, Edmundo Javier ; Gargiulo, Corrado ; Garishvili, I. ; Gerhard, J. ; Germain, Marie ; Gheata, Andrei George ; Gheata, Mihaela ; Ghidini, B. ; Ghosh, Premomoy ; Ghosh, Sanjay Kumar ; Gianotti, Paola ; Giubellino, Paolo ; Gładysz-Dziaduś, Ewa ; Glässel, Peter ; Gomez, R. ; González Zamora, Pedro ; Gorbunov, Sergey ; Görlich, Lidia Maria ; Gotovac, Sven ; Graczykowski, Łukasz Kamil ; Grajcarek, R. ; Grelli, Alessandro ; Grigoras, Alina Gabriela ; Grigoraș, Costin ; Grigoriev, Vladislav A. ; Grigoryan, Ara ; Grigoryan, Smbat ; Grinyov, Boris V. ; Grion, Nevio ; Große-Oetringhaus, Jan Fiete ; Grossiord, Jean-Yves ; Grosso, Raffaele ; Guber, Fedor ; Guernane, Rachid ; Guerzoni, Barbara ; Guilbaud, Maxime Rene Joseph ; Gulbrandsen, Kristjan Herlache ; Gulkanyan, Hrant ; Gunji, Taku ; Gupta, Anik ; Gupta, Ramni ; Khan, K. H. ; Haake, Rüdiger ; Haaland, Øystein Senneset ; Hadjidakis, Cynthia Marie ; Haiduc, Maria ; Hamagaki, Hideki ; Hamar, Gergö ; Hanratty, Luke David ; Hansen, Alexander ; Harris, John W. ; Hartmann, Hermann ; Harton, Austin Vincent ; Hatzifotiadou, Despina ; Hayashi, Shinichi ; Hayrapetyan, A. ; Heckel, Stefan Thomas ; Heide, Markus ; Helstrup, Håvard ; Herghelegiu, Andrei Ionut ; Herrera Corral, Gerardo Antonio ; Hess, Benjamin Andreas ; Hetland, Kristin Fanebust ; Hicks, Bernard ; Hippolyte, Boris ; Hladkỳ, Jan ; Hristov, Peter ; Huang, M. ; Humanic, Thomas J. ; Hutter, Dirk ; Hwang, Dae Sung ; Ianigro, J.-C. ; Ilkaev, Radiy ; Ilkiv, Iryna ; Inaba, Motoi ; Incani, Elisa ; Innocenti, Gian Michele ; Ionita, Costin ; Ippolitov, Mikhail ; Irfan, M. ; Ivanov, Marian ; Ivanov, Vladimir ; Ivanytskyi, Oleksii ; Jacholkowski, Adam Wlodzimierz ; Jahnke, Cristiane ; Jang, Haeng Jin ; Janik, Malgorzata Anna ; Jayarathna, Pahula Hewage Sandun Yasassri ; Jena, Satyajit ; Jiménez Bustamante, Raúl Tonatiuh ; Jones, Peter Graham ; Jung, H. ; Jusko, Anton ; Kalcher, S. ; Kalinak, Peter ; Kalweit, Alexander Philipp ; Kamin, Jason Adrian ; Kang, Ju Hwan ; Kaplin, Vladimir ; Kar, Somnath ; Karasu Uysal, Ayben ; Karavichev, Oleg V. ; Karavicheva, Tatiana L. ; Karpechev, Evgeny ; Kebschull, Udo ; Keidel, Ralf ; Ketzer, Bernhard ; Mohisin Khan, Mohammed ; Khan, P. ; Khan, Shuaib Ahmad ; Khanzadeev, Alexei ; Kharlov, Yury ; Kileng, Bjarte ; Kim, B. ; Kim, D. W. ; Kim, Dong Jo ; Kim, Jin Sook ; Kim, M. ; Kim, M. ; Kim, Se Yong ; Kim, T. ; Kirsch, Stefan ; Kisel, Ivan ; Kiselev, Sergej N. ; Kisiel, Adam Ryszard ; Kiss, Gabor ; Klay, Jennifer Lynn ; Klein, Jochen ; Klein-Bösing, Christian ; Kluge, Alexander ; Knichel, Michael Linus ; Knospe, Anders Garritt ; Kobdaj, Chinorat ; Köhler, Markus Konrad ; Kollegger, Thorsten ; Kolojvari, Anatoly ; Kondratiev, Valery P. ; Kondratyeva, Natalia V. ; Konevskikh, Artem ; Kovalenko, Vladimir ; Kowalski, Marek ; Kox, Serge ; Koyithatta Meethaleveedu, Greeshma ; Kral, Jiří ; Králik, Ivan ; Kramer, F. ; Kravčáková, Adela ; Křelina, Michal ; Kretz, Matthias ; Krivda, Marian ; Krizek, Filip ; Krůs, Miroslav ; Kryshen, Evgeny ; Krzewicki, Mikolaj ; Kučera, Vít ; Kucheriaev, Yury ; Kugathasan, Thanushan ; Kuhn, Christian Claude ; Kuijer, Paulus Gerardus ; Kulakov, Igor ; Kumar, Jitendra ; Kurashvili, Podist ; Kurepin, Alexander ; Kurepin, Alexey B. ; Kuryakin, Alexey ; Kushpil, Svetlana ; Kushpil, V. ; Kweon, Min Jung ; Kwon, Youngil ; Ladron de Guevara, Pedro ; Lagana Fernandes, Caio ; Lakomov, Igor ; Langoy, Rune ; Lara Martinez, Camilo Ernesto ; Lardeux, Antoine Xavier ; Lattuca, Alessandra ; La Pointe, Sarah Louise ; La Rocca, Paola ; Lea, Ramona ; Lee, Graham Richard ; Legrand, Iosif ; Lehnert, Jörg ; Lemmon, Roy Crawford ; Lenhardt, Matthieu Laurent ; Lenti, Vito ; Leogrande, Emilia ; Leoncino, Marco ; León Monzón, Ildefonso ; Lévai, Péter ; Li, S. ; Lien, Jørgen André ; Lietava, Roman ; Lindal, Svein ; Lindenstruth, Volker ; Lippmann, Christian ; Lisa, Michael A. ; Ljunggren, Hans Martin ; Lodato, Davide Francesco ; Lønne, Per-Ivar ; Loggins, Vera Renee ; Loginov, Vitaly ; Lohner, D. ; Loizides, Constantinos ; Lopez, Xavier Bernard ; López Torres, Ernesto ; Lu, X.-G. ; Lüttig, Philipp ; Lunardon, Marcello ; Luo, J. ; Luparello, Grazia ; Luzzi, Cinzia ; Gago Medina, Alberto Martín ; Jacobs, Peter Martin ; Ma, R. ; Maevskaya, Alla ; Mager, Magnus ; Mahapatra, D. P. ; Maire, Antonin ; Malaev, Mikhail ; Maldonado Cervantes, Ivonne Alicia ; Malinina, Liudmila ; Mal'Kevich, Dmitry ; Malzacher, Peter ; Mamonov, Alexander ; Manceau, Loic Henri Antoine ; Manko, Vladislav ; Manso, Franck ; Manzari, Vito ; Marchisone, Massimiliano ; Mareš, Jiří ; Margagliotti, Giacomo Vito ; Margotti, Anselmo ; Marín, Ana ; Markert, Christina ; Marquard, Marco ; Martashvili, Irakli ; Martin, Nicole Alice ; Martinengo, Paolo ; Martínez Hernández, Mario Iván ; Martínez Garcia, Ginés ; Martin Blanco, Javier ; Martynov, Yevgen ; Mas, Alexis Jean-Michel ; Masciocchi, Silvia ; Masera, Massimo ; Masoni, Alberto ; Massacrier, Laure Marie ; Mastroserio, Annalisa ; Matyja, Adam Tomasz ; Mayer, Christoph ; Mazer, Joel Anthony ; Mazumder, Rakesh ; Mazzoni, Alessandra Maria ; Meddi, Franco ; Menchaca-Rocha, Arturo Alejandro ; Mercado Pérez, Jorge ; Meres, Michal ; Miake, Yasuo ; Mikhaylov, Konstantin ; Milano, Leonardo ; Milošević, Jovan ; Mischke, André ; Mishra, Aditya Nath ; Miśkowiec, Dariusz Czesław ; Mitu, Ciprian Mihai ; Mlynarz, J. ; Mohanty, Bedangadas ; Molnar, Levente ; Montaño Zetina, Luis Manuel ; Montes Prado, Esther ; Morando, Maurizio ; Godoy, Denise Aparecida Moreira de ; Moretto, Sandra ; Morreale, Astrid ; Morsch, Andreas ; Muccifora, Valeria ; Mudnic, Eugen ; Muhuri, Sanjib ; Mukherjee, Maitreyee ; Müller, H. ; Munhoz, Marcelo Gameiro ; Murray, Sean ; Musa, Luciano ; Musinsky, Jan ; Nandi, Basanta Kumar ; Nania, Rosario ; Nappi, Eugenio ; Nattrass, Christine ; Nayak, Tapan Kumar ; Nazarenko, Sergey ; Nedosekin, Alexander ; Nicassio, Maria ; Niculescu, Mihai ; Nielsen, Borge Svane ; Nikolaev, Sergey ; Nikulin, Sergey ; Nikulin, Vladimir ; Nilsen, B. 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A measurement of the transverse momentum spectra of jets in Pb-Pb collisions at sNN−−−√=2.76 TeV is reported. Jets are reconstructed from charged particles using the anti-kT jet algorithm with jet resolution parameters R of 0.2 and 0.3 in pseudo-rapidity |η|<0.5. The transverse momentum pT of charged particles is measured down to 0.15 GeV/c which gives access to the low pT fragments of the jet. Jets found in heavy-ion collisions are corrected event-by-event for average background density and on an inclusive basis (via unfolding) for residual background fluctuations and detector effects. A strong suppression of jet production in central events with respect to peripheral events is observed. The suppression is found to be similar to the suppression of charged hadrons, which suggests that substantial energy is radiated at angles larger than the jet resolution parameter R=0.3 considered in the analysis. The fragmentation bias introduced by selecting jets with a high pT leading particle, which rejects jets with a soft fragmentation pattern, has a similar effect on the jet yield for central and peripheral events. The ratio of jet spectra with R=0.2 and R=0.3 is found to be similar in Pb-Pb and simulated PYTHIA pp events, indicating no strong broadening of the radial jet structure in the reconstructed jets with R<0.3.
The gas phase ion chemistry of the simplest known phosphorus ylide, trimethylmethylenephosphorane, has been studied in the mass range m/e=2 - 186 and the pressure range 10-7-10-4 Torr. The most abundant product ion, m/e = 104, (CH3)2C2H5PCH2'+ is formed by a methylene group transfer reaction of the molecular ion. Almost all of the other product ions formed from the molecular ion can be subsumed under the general formula (CH3)3PCHPRn+ (R = H, CH3; n=1,2,3). The reactions indicate that the molecular ion has lost its ylide character almost completely. The protonated molecule is formed almost exclusively by a reaction of the fragment ion m/e = 75. This reaction and the CH3PH group transfer reaction indicate a cyclic structure (CH3) HP(CH2)2+ for this ion. A cyclic structure is also assumed for the ion m/e = 73, PC3H6+, which undergoes P and PH transfer reactions. The reactions of the ion m/e = 47 are consistent with the structure CH3PH+. The ICR and mass spectra are given, some metastable decompositions are discussed.
The mass spectrum and the ion molecule reactions of phosphirane and of mixtures of phosphirane with NH3 , NH2D, NHD2 and ND3 have been studied by ion cyclotron resonance spectrometry. Almost all important product ions are formed by PH-group transfer reactions, where ethene is generated as the neutral particle. Only two of the more abundant ions, the protonated molecule, H2P(CH2)2+ and the ion m/e=63, P2H+, are formed via other reaction pathways. Secondary, tertiary and quarternary product ions with the general formula R(PH)n+ (R: phosphirane fragment, n-1, 2, 3) have been detected.
The molecular ion is proved to have a cyclic structure. Two possible structures of the product ions with two and three phosphorus atoms are discussed: a structure with an open phosphorus chain, leaving the phosphirane ring intact and a ring extended structure, produced by a ring extension reaction of the PH-group.
Several rate constants of the ion molecule reactions of the phosphirane molecular ion are given.
Es wird das Mikrowellenspektrum von Fluorwasserstoffassoziaten im X-und K-Band bei -70 °C und 0,01 Torr gemessen und analysiert. Dazu wird ein erstelltes Frequenzprogramm für den asymmetrischen Kreisel verwendet, sowie ein Extrapolationsprogramm, das eine in der Literatur angegebene druck-und temperaturabhängige Verteilung der Fluorwasserstoffassoziate auf für Mikrowellenspektroskopie geeignete Drücke und Temperaturen umzurechnen erlaubt. Es zeigt sich, daß planare hexamere und heptamere Fluorwasserstoffassoziate vorliegen mit F-F-F-Winkeln von etwa 104° und H-F-Bindungslängen von 0,9997 Å bzw. 0,9640 Å. Die Längen der Wasserstoff brücken sind 1,4998 Å bzw. 1,6105 Å. Ein Vergleich der Bindungslängen zeigt, daß bei Anlagerung von H-F an (HF)6 eine Kontraktion der Fluorwasserstoffbindung um 3,5% und eine Dilatation der Wasserstoffbrückenbindung um 1% stattfindet. Dieses Ergebnis steht im Einklang mit der oben erwähnten Assoziatverteilung, die eine Minderung der Kettenstabilität beim Übergang von hexamerer zu heptamerer Kette erwarten läßt.
The ion-molecule reactions of thiothionylfluoride have been studied by ion cyclotron resonance spectrometry. The major secondary ions are S2F3+ , S3F+ , and S3F2+. In a consecutive reaction of S3F2+ the tertiary ion S4F2+ is formed. The rate constant of the IMR with the greatest yield S2F2+ + SSF2 → S3F2+ + SF was estimated to k = 2 · 10-9 cm 3 molecule -1 sec -1 . The results were compared with the mass spectrum of thiothionylfluoride. They permit conclusions on chemical reactions of lower sulphurfluorides.
Es wird das Mikrowellenspektrum eines symmetrischen Kreisels (tert.-Butyljodid) untersucht, in dem sich die HFS-Komponenten des Schwingungsgrundzustandes mit denen einiger angeregten Vibrationszustände überlagern. Dabei gelingt es, eine allgemeine Methode zur Analyse eines mit den genannten Schwierigkeiten behafteten Spektrums zu entwickeln. Die Auswertung ergibt im Falle des tert.-Butyljodids folgende Konstanten: e Q q = -1709,5 ± 5,5 MHz, B = 1560,60 ± 0,01 MHz, DJ = 0,20 ± 0,10 kHz, DJK = 0,70 ± 0,07 kHz, rC-J = 2,190 ± 0,005 Å.
The nuclear magnetic resonance of 133Cs (I=7/2) has been studied at room temperature in the isostructural compounds Cs2CuCl4, Cs2CuBr4, Cs2CoCl4 and Cs2ZnCl4. The nuclear quadrupole coupling tensors and the magnetic shift tensors have been determined at the two inequivalent sites of the unit cell for all complexes. A satisfactory description of the quadrupole coupling (νq ≲ 20 kc) with a point charge model is only possible by reducing the charge on the central ion of the MX4 tetrahedron to +1-1. Large isotropic shifts (up to 0.5%) with smaller anisotropic contributions have been found in the paramagnetic compounds. The diamagnetic Cs2ZnCl4 shows shift up to 0.03% relative to CsCl.
The microwave spectra of SiFBr3 and CH3SiBr have been investigated in the region from 30 to 40 GHz. Assuming reasonable values for dSi-F, dSi-C and the methyl group a least squares analysis of the rotational constants yields dSi-Br ≮Br—Si—Br SiFBr3 (2,171 ± 0,001) A (111,36 ± 0,15)°, CH3SiBr3 (2,175±0,001) A (111,09±0,15)°. A barrier to internal rotation of about 1 kcal/mole is estimated by the intensity method.