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A canonical partition function for the two-component excluded volume model is derived, leading to two di erent van der Waals approximations. The one is known as the Lorentz-Berthelot mixture and the other has been proposed recently. Both models are analysed in the canonical and grand canonical ensemble. In comparison with the one-component van der Waals excluded volume model the suppression of particle densities is reduced in these two-component formulations, but in two essentially di erent ways. Presently used multi-component models have no such reduction. They are shown to be not correct when used for components with di erent hard-core radii. For high temperatures the excluded volume interaction is refined by accounting for the Lorentz contraction of the spherical excluded volumes, which leads to a distinct enhancement of lighter particles. The resulting e ects on pion yield ratios are studied for AGS and SPS data.
Conventional cluster and virial expansions are generalized to momentum dependent interparticle potentials. The model with Lorentz contracted hard core potentials is considered, e.g. as hadron gas model. A Van der Waals-type model with a temperature dependent excluded volume is derived. Lorentz contraction effects at given temperature are stronger for light particles and make their effective excluded volume smaller than that of heavy ones.