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In recent decades, mass spectrometry has moved more than ever before into the front line of protein-centered research. After being established at the qualitative level, the more challenging question of quantification of proteins and peptides using mass spectrometry has become a focus for further development. In this chapter, we discuss and review actual strategies and problems of the methods for the quantitative analysis of peptides, proteins, and finally proteomes by mass spectrometry. The common themes, the differences, and the potential pitfalls of the main approaches are presented in order to provide a survey of the emerging field of quantitative, mass spectrometry-based proteomics.
This chapter reviews the boron isotopic composition of the ocean floor, including pristine igneous oceanic crust such as mid-ocean ridge basalts and ocean island basalts and their implications for the B isotopic composition of the mantle. The chapter further discusses the B isotopic effects of assimilation of altered crustal materials in mantle-derived magmas. The systematics of seawater alteration on oceanic rocks are discussed, including sediments, igneous crust and serpentinization of ultramafic rocks and the respective marine hydrothermal vent fluids. The chapter concludes with a discussion of the secular evolution of the B isotopic composition of seawater.
This paper analyses, if the Intertemporal Guarantee of Freedom, that was developed by the German Federal Constitutional Court (GFCC), can be used to expand the protection of human rights against the harms of climate change. The case of the Swiss Senior Women shows that there are jurisdictions, where the Intertemporal Guarantee of Freedom could be applied to improve standing and the control standard of states’ climate change action. Within international law bodies with jurisdiction over human rights treaties there are distinctive standards of protection against the harms of climate change. A major deficit within the international human rights protection against climate change lies within the focus on the positive obligations and the corresponding wide margin of appreciation granted to the states. The Intertemporal Guarantee of Freedom could provide a protection expansion in this regard, especially in the case of the European Court of Human Rights. It could also enable and legitimise present human rights concerns focused on the future actions of states following their past inaction. One considerable hurdle that is not addressed by it are procedural hurdles like the Plaumann formula applied by the European Court of Justice. The Intertemporal Guarantee of Freedom cannot solve major problems for climate change litigation like procedural hurdles. Yet, it can provide a new approach for complaints to address unambitious mitigation legislation which will lead to future human rights infringements.
Enabling cybersecurity and protecting personal data are crucial challenges in the development and provision of digital service chains. Data and information are the key ingredients in the creation process of new digital services and products. While legal and technical problems are frequently discussed in academia, ethical issues of digital service chains and the commercialization of data are seldom investigated. Thus, based on outcomes of the Horizon2020 PANELFIT project, this work discusses current ethical issues related to cybersecurity. Utilizing expert workshops and encounters as well as a scientific literature review, ethical issues are mapped on individual steps of digital service chains. Not surprisingly, the results demonstrate that ethical challenges cannot be resolved in a general way, but need to be discussed individually and with respect to the ethical principles that are violated in the specific step of the service chain. Nevertheless, our results support practitioners by providing and discussing a list of ethical challenges to enable legally compliant as well as ethically acceptable solutions in the future.
Previous research on scalar implicature has primarily relied on metalinguistic judgment tasks and found varying rates of such inferences depending on the nature of the task and contextual manipulations. This paper introduces a novel interactive paradigm involving both a production and a comprehension component, thereby fixing a precise conversational context.
The main research question is what is reliably communicated by some in this communicative setting, when the quantifier occurs in unembedded positions as well as embedded positions. Our new paradigm involves an action-based task from which participants’ interpretation of utterances can be inferred. It incorporates a game–theoretic design, including a precise model to predict participants’ behaviour in the experimental context.
Our study shows that embedded and unembedded implicatures are reliably communicated by some. We propose two cognitive principles which describe what can be left unsaid. In our experimental context, a production strategy based on these principles is more efficient (with equal communicative success and shorter utterances) than a strategy based on literal descriptions.