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A recent paper on energy dependence of strangeness production in A+A and p+p interactions written by Dunlop and Ogilvie (Phys. ReV. C61 031901(R) (2000) indicates that there is a significant misunderstanding about the concept of strangeness enhancement and its role as a signal of Quark Gluon Plasma creation. In this comment we will try to clarify some essential points. 25.75.Dw, 13.85.Ni, 21.65.+f
A validity of a recent estimate of an upper limit of charm production in central Pb+Pb collisions at 158 AGeV is critically discussed. Within a simple model we study properties of the background subtraction procedure used for an extraction of the charm signal from the analysis of dilepton spectra. We demonstrate that a production asymmetry between positively and negatively charged background muons and a large multiplicity of signal pairs leads to biased results. Therefore the applicability of this procedure for the analysis of nucleus-nucleus data should be reconsidered before final conclusions on the upper limit estimate of charm production could be drawn.
The hypothesis of statistical production of J/psi mesons at hadronization is formulated and checked against experimental data. It explains in the natural way the observed scaling behavior of the J/psi to pion ratio at the CERN SPS energies. Using the multiplicities of J/psi and eta mesons the hadronization temperature T_H = 175 MeV is found, which agrees with the previous estimates of the temperature parameter based on the analysis of the hadron yield systematics.
The experimental results on the pion, strangeness and J/psi production in high energy nuclear collisions are discussed. The anomalous energy dependence of pion and strangeness production is consistent with the hypothesis that a transition to a deconfined phase takes place between the top AGS (15 AGeV) and the SPS (200 AGeV) energies. The J/psi production systematics at the SPS can be understood assuming that the J/psi mesons are created at hadronization according to the available hadronic phase space. This new interpretation of the J/psi data allows one to establish a coherent picture of high energy nuclear collisions based on the statistical approaches of the collision early stage and hadronization. Surprisingly, the statistical model of strong interactions is successful even in the region reserved up to now for pQCD based models.
The statistical production of antibaryons is considered within the canonical ensemble formulation. We demonstrate that the antibaryon suppression in small systems due to the exact baryon number conservation is rather different in the baryon-free (B=0) and baryon-rich (B>1) systems. At constant values of temperature and baryon density in the baryon-rich systems the density of the produced antibaryons is only weakly dependent on the size of the system. For realistic hadronization conditions this dependence appears to be close to B/(B+1) which is in agreement with the preliminary data of the NA49 Collaboration for the antiproton/pion ratio in nucleus-nucleus collisions at the CERN SPS energies. However, a consistent picture of antibaryon production within the statistical hadronization model has not yet been achieved. This is because the condition of constant hadronization temperature in the baryon-free systems leads to a contradiction with the data on the antiproton/pion ratio in e+e- interactions.
The data on average hadron multiplicities in central A+A collisions measured at CERN SPS are analysed with the ideal hadron gas model. It is shown that the full chemical equilibrium version of the model fails to describe the experimental results. The agreement of the data with the off-equilibrium version allowing for partial strangeness saturation is significantly better. The freeze-out temperature of about 180 MeV seems to be independent of the system size (from S+S to Pb+Pb) and in agreement with that extracted in e+e-, pp and p{\bar p} collisions. The strangeness suppression is discussed at both hadron and valence quark level. It is found that the hadronic strangeness saturation factor gamma_S increases from about 0.45 for pp interactions to about 0.7 for central A+A collisions with no significant change from S+S to Pb+Pb collisions. The quark strangeness suppression factor lambda_S is found to be about 0.2 for elementary collisions and about 0.4 for heavy ion collisions independently of collision energy and type of colliding system
It is shown that data on pion and strangeness production in central nucleus-nucleus collisions are consistent with the hypothesis of a Quark Gluon Plasma formation between 15 A GeV/c (BNL AGS) and 160 A GeV/c (CERN SPS) collision energies. The experimental results interpreted in the framework of a statistical approach indicate that the effective number of degrees of freedom increases by a factor of about 3 in the course of the phase transition and that the plasma created at CERN SPS energy may have a temperature of about 280 MeV (energy density $\approx$ 10 GeV/fm^3). Experimental studies of central Pb+Pb collisions in the energy range 20-160 A GeV/c are urgently needed in order to localize the threshold energy, and study the properties of the QCD phase transition.
The pion multiplicity per participating nucleon in central nucleus-nucleus collisions at the energies 2-15 A GeV is significantly smaller than in nucleon-nucleon interactions at the same collision energy. This effect of pion suppression is argued to appear due to the evolution of the system produced at the early stage of heavy-ion collisions towards a local thermodynamic equilibrium and further isentropic expansion.
We demonstrate that a new type of analysis in heavy-ion collisions, based on an event-by-event analysis of the transverse momentum distribution, allows us to obtain information on secondary interactions and collective behaviour that is not available from the inclusive spectra. Using a random walk model as a simple phenomenological description of initial state scattering in collisions with heavy nuclei, we show that the event-by-event measurement allows a quantitative determination of this effect, well within the resolution achievable with the new generation of large acceptance hadron spectrometers. The preliminary data of the NA49 collaboration on transverse momentum fluctuations indicate qualitatively different behaviour than that obtained within the random walk model. The results are discussed in relation to the thermodynamic and hydrodynamic description of nuclear collisions.
We present a detailed study of chemical freeze-out in nucleus-nucleus collisions at beam energies of 11.6, 30, 40, 80 and 158A GeV. By analyzing hadronic multiplicities within the statistical hadronization approach, we have studied the strangeness production as a function of centre of mass energy and of the parameters of the source. We have tested and compared different versions of the statistical model, with special emphasis on possible explanations of the observed strangeness hadronic phase space under-saturation. We show that, in this energy range, the use of hadron yields at midrapidity instead of in full phase space artificially enhances strangeness production and could lead to incorrect conclusions as far as the occurrence of full chemical equilibrium is concerned. In addition to the basic model with an extra strange quark non-equilibrium parameter, we have tested three more schemes: a two-component model superimposing hadrons coming out of single nucleon-nucleon interactions to those emerging from large fireballs at equilibrium, a model with local strangeness neutrality and a model with strange and light quark non-equilibrium parameters. The behaviour of the source parameters as a function of colliding system and collision energy is studied. The description of strangeness production entails a non-monotonic energy dependence of strangeness saturation parameter gamma_S with a maximum around 30A GeV. We also present predictions of the production rates of still unmeasured hadrons including the newly discovered Theta^+(1540) pentaquark baryon.
The data on mT spectra of K0S K+ and K- mesons produced in all inelastic p + p and p + pbar interactions in the energy range sqrt(s)NN=4.7-1800GeV are compiled and analyzed. The spectra are parameterized by a single exponential function, dN/(m_T*dm_T)=C exp(-m_T/T), and the inverse slope parameter T is the main object of study. The T parameter is found to be similar for K0S, K+ and K- mesons. It increases monotonically with collision energy from T~30MeV at sqrt(s)NN=4.7GeV to T~220MeV at sqrt(s)NN=1800GeV. The T parameter measured in p+p and p+pbar interactions is significantly lower than the corresponding parameter obtained for central Pb+Pb collisions at all studied energies. Also the shape of the energy dependence of T is different for central Pb+Pb collisions and p+p(pbar) interactions.
The history and the main results of the energy scan program at the CERN SPS are reviewed. Several anomalies in energy dependence of hadron production predicted as signals of deconfinement phase transition are observed and they indicate that the onset of deconfinement is located at about 30 A GeV. For the first time we seem to have clear evidence for the existence of a deconfined state of matter in nature.
We propose a method to experimentally study the equation of state of strongly interacting matter created at the early stage of nucleus--nucleus collisions. The method exploits the relation between relative entropy and energy fluctuations and equation of state. As a measurable quantity, the ratio of properly filtered multiplicity to energy fluctuations is proposed. Within a statistical approach to the early stage of nucleus-nucleus collisions, the fluctuation ratio manifests a non--monotonic collision energy dependence with a maximum in the domain where the onset of deconfinement occurs.
We present a detailed study of chemical freeze-out in nucleus-nucleus collisions at beam energies of 11.6, 30, 40, 80 and 158A GeV. By analyzing hadronic multiplicities within the statistical hadronization approach, we have studied the chemical equilibration of the system as a function of center of mass energy and of the parameters of the source. Additionally, we have tested and compared different versions of the statistical model, with special emphasis on possible explanations of the observed strangeness hadronic phase space under-saturation.
Difficulties of the thermodynamical model approach to pion production in relativistic ion collisions
(1983)
Thermodynamical models with various forms of partial transparency of nuclear matter are considered. It is shown that the introduction of transparency, however, significantly improves agreement with pion data concerning multiplicities and transverse momenta leads to a serious discrepancy with average rapidities of pions. Qualitative arguments are given that difficulties of the thermodynamical approach can be overcome if one assumes hydrodynamical expansion in the first stage of nuclear interactions.
Transverse momenta and rapidities of Lambda 's produced in central nucleus-nucleus collisions at 4.5 GeV/c·u (C-C,...,O-Pb) were studied and compared with those from inelastic He-Li interactions at the same incident momentum. Polarization of the Lambda hyperons was found to be consistent with zero ( alpha P=-0.06=0.11 for Lambda 's from central collisions). An upper limit of the Lambda -bar / Lambda production ratio was estimated to be less than 4.5 x 10-3. The experiment was performed in a triggered streamer chamber.
Transverse momentum event-by-event fluctuations are studied within the string-hadronic model of high energy nuclear collisions, LUCIAE. Data on non-statistical pT fluctuations in p+p interactions are reproduced. Fluctuations of similar magnitude are predicted for nucleus-nucleus collisions, in contradiction to the preliminary NA49 results. The introduction of a string clustering mechanism (Firecracker Model) leads to a further, significant increase of pT fluctuations for nucleus-nucleus collisions. Secondary hadronic interactions, as implemented in LUCIAE, cause only a small reduction of pT fluctuations.
We argue that the measurement of open charm gives a unique opportunity to test the validity of pQCD-based and statistical models of nucleus-nucleus collisions at high energies. We show that various approaches used to estimate D-meson multiplicity in central Pb+Pb collisions at 158 A GeV give predictions which differ by more than a factor of 100. Finally we demonstrate that decisive experimental results concerning the open charm yield in A+A collisions can be obtained using data of the NA49 experiment at the CERN SPS.
A systematic analysis of data on strangeness and pion production in nucleon–nucleon and central nucleus–nucleus collisions is presented. It is shown that at all collision energies the pion/baryon and strangeness/pion ratios indicate saturation with the size of the colliding nuclei. The energy dependence of the saturation level suggests that the transition to the Quark Gluon Plasma occurs between 15 A·GeV/c (BNL AGS) and 160 A·GeV/c (CERN SPS) collision energies. The experimental results interpreted in the framework of a statistical approach show that the effective number of degrees of freedom increases in the course of the phase transition and that the plasma created at CERN SPS energies may have a temperature of about 280 MeV (energy density ~ 10 GeV/fm exp-3). The presence of the phase transition can lead to the non–monotonic collision energy dependence of the strangeness/pion ratio. After an initial increase the ratio should drop to the characteristic value for the QGP. Above the transition region the ratio is expected to be collision energy independent. Experimental studies of central Pb+Pb collisions in the energy range 20–160 A·GeV/c are urgently needed in order to localize the threshold energy, and study the properties of the QCD phase transition.
Fluctuations and NA49
(2005)
The transverse mass spectra of J/psi and psi' mesons and Omega hyperons produced in central Au+Au collisions at RHIC energies are discussed within a statistical model used successfully for the interpretation of the SPS results. The comparison of the presented model with the future RHIC data should serve as a further crucial test of the hypothesis of statistical production of charmonia at hadronization. Finally, in case of validity, the approach should allow to estimate the mean transverse flow velocity at the quark gluon plasma hadronization.
Fluctuations of charged particle number are studied in the canonical ensemble. In the infinite volume limit the fluctuations in the canonical ensemble are different from the fluctuations in the grand canonical one. Thus, the well-known equivalence of both ensembles for the average quantities does not extend for the fluctuations. In view of a possible relevance of the results for the analysis of fluctuations in nuclear collisions at high energies, a role of the limited kinematical acceptance is studied.
The transverse mass spectra of Omega, J/psi and psi' in Pb+Pb collisions at 158 AGeV are studied within a hydrodynamical model of the quark gluon plasma expansion and hadronization. The model reproduces the existing data with the common hadronization parameters: temperature T=T_H = 170 MeV and average collective transverse velocity v_T = 0.2.
Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at sqrt[sNN] = 130 GeV using the STAR Time Projection Chamber at the Relativistic Heavy Ion Collider. The elliptic flow signal, v2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.
Measurements of the π±, K±, and proton double differential yields emitted from the surface of the 90-cm-long carbon target (T2K replica) were performed for the incoming 31 GeV/c protons with the NA61/SHINE spectrometer at the CERN SPS using data collected during 2010 run. The double differential π± yields were measured with increased precision compared to the previously published NA61/SHINE results, while the K± and proton yields were obtained for the first time. A strategy for dealing with the dependence of the results on the incoming proton beam profile is proposed. The purpose of these measurements is to reduce significantly the (anti)neutrino flux uncertainty in the T2K long-baseline neutrino experiment by constraining the production of (anti)neutrino ancestors coming from the T2K target.
We present measurements of ρ0, ω and K∗0 spectra in π−+ C production interactions at 158 GeV / c and ρ0 spectra at 350 GeV / c using the NA61/SHINE spectrometer at the CERN SPS. Spectra are presented as a function of the Feynman’s variable xF in the range 0<xF<1 and 0<xF<0.5 for 158 and 350 GeV / c respectively. Furthermore, we show comparisons with previous measurements and predictions of several hadronic interaction models. These measurements are essential for a better understanding of hadronic shower development and for improving the modeling of cosmic ray air showers.
his Erratum replaces incorrect plots shown in Fig. 7 with the corrected ones. In the publication, the NA57 [1] ratios of Ξ− and Ξ¯¯¯¯+ to the number of wounded nucleons at ⟨NW⟩=349 by mistake were plotted at the wrong values. The ratios were calculated and plotted by mistake using ⟨NW⟩=249.
The correct normalization does not change the conclusions of the paper. The correctly normalized results are presented in Fig. 7.
The production of Ξ(1321)− and Ξ¯¯¯¯(1321)+ hyperons in inelastic p+p interactions is studied in a fixed target experiment at a beam momentum of 158 GeV/c. Double differential distributions in rapidity y and transverse momentum pT are obtained from a sample of 33M inelastic events. They allow to extrapolate the spectra to full phase space and to determine the mean multiplicity of both Ξ− and Ξ¯¯¯¯+. The rapidity and transverse momentum spectra are compared to transport model predictions. The Ξ− mean multiplicity in inelastic p+p interactions at 158 GeV/c is used to quantify the strangeness enhancement in A+A collisions at the same centre-of-mass energy per nucleon pair.
The physics goal of the strong interaction program of the NA61/SHINE experiment at the CERN Super Proton Synchrotron (SPS) is to study the phase diagram of hadronic matter by a scan of particle production in collisions of nuclei with various sizes at a set of energies covering the SPS energy range. This paper presents differential inclusive spectra of transverse momentum, transverse mass and rapidity of π− mesons produced in central 40Ar+45Sc collisions at beam momenta of 13A, 19A, 30A, 40A, 75A and 150A Ge V /c. Energy and system size dependence of parameters of these distributions – mean transverse mass, the inverse slope parameter of transverse mass spectra, width of the rapidity distribution and mean multiplicity – are presented and discussed. Furthermore, the dependence of the ratio of the mean number of produced pions to the mean number of wounded nucleons on the collision energy was derived. The results are compared to predictions of several models.
A measurement of charged hadron pair correlations in two-dimensional ηφ space is presented. The analysis is based on total 30 million central Be + Be collisions observed in the NA61/SHINE detector at the CERN SPS for incident beam momenta of 19A, 30A, 40A, 75A, and 150A GeV/c. Measurements were carried out for unlike-sign and like-sign charge hadron pairs independently. The C(η, φ) correlation functions were compared with results from a similar analysis on p + p interactions at similar beam momenta per nucleon. General trends of the backto-back correlations are similar in central Be + Be collisions and p + p interactions, but are suppressed in magnitude due to the increased combinatorial background. Predictions from the Epos and UrQMD models are compared to the measurements. Evolution of an enhancement around (η, φ) = (0, 0) with incident energy is observed in central Be + Be collisions. It is not predicted by both models and almost non-existing in proton–proton collisions at the same momentum per nucleon.
We propose to use the hadron number fluctuations in the limited momentum regions to study the evolution of initial flows in high energy nuclear collisions. In this method by a proper preparation of a collision sample the projectile and target initial flows are marked in fluctuations in the number of colliding nucleons. We discuss three limiting cases of the evolution of flows, transparency, mixing and reflection, and present for them quantitative predictions obtained within several models. Finally, we apply the method to the NA49 results on fluctuations of the negatively charged hadron multiplicity in Pb+Pb interactions at 158A GeV and conclude that the data favor a hydrodynamical model with a significant degree of mixing of the initial flows at the early stage of collisions.
Transverse activity of kaons and deconfinement phase transition in nucleus–nucleus collisions
(2003)
We found that the experimental results on transverse mass spectrum of kaons produced in central Pb+Pb (Au+Au) collisions show an anomalous dependence on the colliding energy. The inverse slope of the spectrum increases with the energy in the low (AGS) and high (RHIC) energy domains, whereas it remains constant in the intermediate (SPS) energy range. We argue that this anomaly is probably caused by the modification of the equation of state in the transition region between confined and deconfined matter. This observation may be considered as a new signal, in addition to the previously reported anomalies in the pion and strangeness production, of the onset of deconfinement located in the low SPS energy domain.
In high energy p(p)+p interactions the mean multiplicity and transverse mass spectra of neutral mesons from η to ϒ (m≅0.5–10 GeV/c2) and the transverse mass spectra of pions (mT> 1 GeV/c2) reveal a remarkable behaviour: they follow, over more than 10 orders of magnitude, the power-law function: Cm(T)−P. The parameters C and P are energy dependent, but similar for all mesons produced at the same collision energy. This scaling resembles that expected in the statistical description of hadron production: the parameter P plays the role of a temperature and the normalisation constant C is analogous to the system volume. The fundamental difference is, however, in the form of the distribution function. In order to reproduce the experimental results and preserve the basic structure of the statistical approach the Boltzmann factor e−E∗/T appearing in standard statistical mechanics has to be substituted by a power-law factor (E∗/Λ)−P.
We propose a method to experimentally study the equation of state of strongly interacting matter created at the early stage of nucleus–nucleus collisions. The method exploits the relation between relative entropy and energy fluctuations and equation of state. As a measurable quantity, the ratio of properly filtered multiplicity to energy fluctuations is proposed. Within a statistical approach to the early stage of nucleus–nucleus collisions, the fluctuation ratio manifests a non-monotonic collision energy dependence with a maximum in the domain where the onset of deconfinement occurs.
We suggest that the fluctuations of strange hadron multiplicity could be sensitive to the equation of state and microscopic structure of strongly interacting matter created at the early stage of high energy nucleus–nucleus collisions. They may serve as an important tool in the study of the deconfinement phase transition. We predict, within the statistical model of the early stage, that the ratio of properly filtered fluctuations of strange to non-strange hadron multiplicities should have a non-monotonic energy dependence with a minimum in the mixed phase region.
Development of fragmented low-Z ion beams for the NA61 fixed-target experiment at the CERN SPS
(2011)
The NA61 experiment, aims to study the properties of the onset of deconfinement at low SPS energies and to find signatures of the critical point of strongly interacting matter. A broad range in T-μB phase diagram will be covered by performing an energy (13A-158A GeV/c) and system size (p+p, Be+Be, Ar+Ca, Xe+La) scan. In a first phase, fragmented ion beams of 7Be or 11C produced as secondaries with the same momentum per nucleon when the incident primary Pb-ion beam hits a thin Be target will be used. The H2 beam line that transports the beam to the experiment acts as a double spectrometer which combined with a new thin target (degrader) where fragments loose energy proportional to the square of their charge allows the separation of the wanted A/Z fragments. Thin scintillators and TOF measurement for the low energy points are used as particle identification devices. In this paper results from the first test of the fragmented ion beam done in 2010 will be presented showing that a pure Be beam can be obtained satisfying the needs of the experiment.
System size dependence of hadron production properties is discussed within the Wounded Nucleon Model and the Statistical Model in the grand canonical, canonical and micro-canonical formulations. Similarities and differences between predictions of the models related to the treatment of conservation laws are exposed. A need for models which would combine a hydrodynamicallike expansion with conservation laws obeyed in individual collisions is stressed.
The pion multiplicity per participating nucleon in central nucleus-nucleus collisions at the energies 2-15 A GeV is significantly smaller than in nucleon-nucleon interactions at the same collision energy. This effect of pion suppression is argued to appear due to the evolution of the system produced at the early stage of heavy-ion collisions towards a local thermodynamic equilibrium and further isentropic expansion.
The transverse mass spectra of J/ψ and ψ′ mesons and Ω hyperons produced in central Au+Au collisions at RHIC energies are discussed within a statistical model used successfully for the interpretation of the SPS results. The comparison of the presented model with the future RHIC data should serve as a further crucial test of the hypothesis of statistical production of charmonia at hadronization. Finally, in case of validity, the approach should allow to estimate the mean transverse flow velocity at the quark–gluon plasma hadronization.
Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at sqrt(s_NN)=130 GeV using the STAR TPC at RHIC. The elliptic flow signal, v_2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.
Charmonium production in heavy ion collisions is considered as an important diagnostic probe for studying the phase diagram of strongly interacting matter for potential phase transitions. The interpretation of existing data from the CERN SPS is hampered by a lack of knowledge on the properties of open charm particle production in the fireball. Moreover, open charm production in heavy ion collisions by itself is poorly understood. To overcome this obstacle, the NA61/SHINE was equipped with a Small Acceptance Vertex Detector (SAVD), which is predicted to make the experiment sensitive to open charm mesons produced in A-A collisions at the SPS top energy. This paper will introduce the concept and the hardware of the SAVD. Moreover, first running experience as obtained in a commissioning run with a 150 AGeV/c Pb+Pb collision system will be reported.
Twenty years ago, on February 10, 2000, the CERN Director General Luciano Maiani announced: The combined data coming from the seven experiments on CERN’s Heavy Ion programme have given a clear picture of a new state of matter. This result verifies an important prediction of the present theory of fundamental forces between quarks. This report briefly reviews studies of the phase diagram of strongly interacting matter with relativistic nuclear collisions at the CERN Super Proton Synchrotron which followed the CERN’s press release on the quark-gluon plasma discovery. An attempt to formulate priorities for future measurements at the CERN SPS closes the paper. The report is dedicated to David Blaschke who celebrated his 60th birthday in 2019. David’s contribution to the studies presented here was very significant.
A new SPS programme
(2006)
A new experiemntal program to study hadron production in hadron-nucleus and nucleus-nucleus collisions at the CERN SPS has been recently proposed by the NA49-future collaboration. The physics goals of the program are: (i) search for the critical point of strongly interacting matter and a study of the properties of the onset of deconfinemnt in nucleus-nucleus collisions, (ii) measurements of correlations, fluctuations and hadron spectra at high transverse momentum in proton-nucleus collisions needed as for better understanding of nucleus-nucleus results, (iii) measurements of hadron production in hadron-nucleus interactions needed for neutrino (T2K) and cosmic-ray (Pierre Auger Observatory and KASCADE) expriments. The physics of the nucleus-nucleus program is reviewed in this presentation.
We present a detailed study of chemical freeze-out in p-p, C-C, Si-Si and Pb-Pb collisions at beam momenta of 158A GeV as well as Pb-Pb collisions at beam momenta of 20A, 30A, 40A and 80A GeV. By analyzing hadronic multiplicities within the statistical hadronization model, we have studied the parameters of the source as a function of the number of the participating nucleons and the beam energy. We observe a nice smooth behaviour of temperature, baryon chemical potential and strangeness under-saturation parameter as a function of energy and nucleus size. Interpolating formulas are provided which allow to predict the chemical freeze-out parameters in central collisions at centre-of-mass energies > 4.5 GeV and for any colliding ions. Specific discrepancies between data and model emerge in particle ratios in Pb-Pb collisions at SPS between 20A and 40A GeV of beam energy which cannot be accounted for in the considered model schemes.