Untersuchungen zur Reaktivität des Lithiumphosphanids Li[PtBu2] gegenüber GaCl3
Investigations of the reactivity of the lithiumphosphanide Li[PtBu2] towards GaCl3
- Single crystals suitable for X-ray diffraction of (tBu2P)3Ga (monoclinic, space group Cc) were obtained from GaCl3 and two equivalents of Li[PtBu2] at room temperature in benzene. The phosphanylgallane (tBu2P)3Ga was also produced via a one-pot approach by reaction of GaCl3 with three or more than three equivalents of Li[PtBu2]. However, treatment of one equivalent of GaCl3 with one equivalent of Li[PtBu2] and subsequent protolysis yielded [tBu2PH2][tBu2P(GaCl3)2 - Li(Cl3Ga)2PtBu2]. Single crystals of this phosphonium salt (monoclinic, space group Cc) were obtained from benzene at room temperature.
| Author: | Hans-Wolfram LernerORCiDGND, Inge Sänger, Frauke Schödel, Michael BolteORCiD, Matthias WagnerORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-809562 |
| DOI: | https://doi.org/10.1515/znb-2011-0708 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 2011 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/26 |
| Tag: | Addition Compounds; Gallium; Phosphorus; X-Ray Structure Analysis |
| Volume: | 66.2011 |
| Issue: | 7 |
| Page Number: | 5 |
| First Page: | 695 |
| Last Page: | 699 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
