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Additionsverbindungen von Methylhalogensiianen und Pyridin bei tiefen Temperaturen

Addition compounds of methylhalogenosilanes and pyridine at low temperatures

  • By analyzing the melting point diagrams of some methylhalogenosilane-pyridine systems the existance of the stable addition compounds CH3SiCl3 · 2 py, CH3SiBr3 · 2 py, (CH3)2SiBr2 · py, (CH3)3SiBr · py was proved. In the systems (CH3)2SiCl2/py and (CH3)2SiBr2/py unstable 1:2-complexes are also found. (CH3)3SiCl forms no complexes with pyridine.

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Metadaten
Author:Karl Hensen, Reiner Busch
URN:urn:nbn:de:hebis:30:3-719643
DOI:https://doi.org/10.1515/znb-1982-0915
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1982
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2024/01/10
Tag:Melting Point Diagrams; Methylhalogenosilanes; Pyridine
Volume:37.1982
Issue:9
Page Number:4
First Page:1174
Last Page:1177
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0