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Synthese von vier- und achtgliedrigen Heterocyclen, die Schwefel, Stickstoff und Phosphor enthalten, und die Röntgenstrukturanalyse eines phosphorhaltigen achtgliedrigen SN-Ringes
Synthesis of four- and eight-membered heterocycles containing sulfur, nitrogen and phosphorus and the X-ray structure of a phosphorus-containing eight-membered SN-ring
- Eight-membered rings of the composition [SO2(NR)2PR′]2 3a-d with R = CH3, C2H5, and R′ = CH3, C6H5, were prepared from substituted sulfamides and dichlorophosphanes in the presence of a tertiary amine. These molecules were characterized on the basis of 1H and 31P NMR investigations and of mass spectra. 3 a reacts with phosphorus pentachloride to yield the spirocyclic derivative 4 with the phosphorus atom in the center of two four-membered rings. Methyliodide reacts with 3 a and 3 b under opening of the eight- membered ring and formation of phosphonium salts. The structure of 3 b is discussed in detail. 8b crystallizes in the orthorhombic space group Pna 21 with a = 12.60(0), b = 13.27(1), c = 12.62(4) Å.
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| Author: | Herbert W. RoeskyORCiDGND, Sushil K. Mehrotra, Christoph Platte, Djamrnschid Amirzadeh-Asl, Bernhard RothGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719392 |
| DOI: | https://doi.org/10.1515/znb-1980-0912 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1980 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | Cyclic Sulfonyl Derivatives; Phosphonium Salts; Spiro Compounds; X-ray |
| Volume: | 35.1980 |
| Issue: | 9 |
| Page Number: | 7 |
| First Page: | 1130 |
| Last Page: | 1136 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
