Photoelectron spectra and molecular properties, XLVIII. Carbonates and thiocarbonates
- Photoelectron (PE) spectra of ethylene and vinylene carbonates and thiocarbonates as well as of methylene trithiocarbonate and some open-chain derivatives are reported. The low energy bands, well separated in the unsaturated compounds, are assigned to lone pair and π type ionizations. The assignment is based on comparison of PE spectra, modified CNDO calculations, and sulfur Κβ emission spectra. The pronounced substituent effects due to which the first ionization potential varies from 8.4 eV to 11.1 eV are discussed.
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| Author: | Klaus Wittel, Eva Elisabeth AstrupGND, Hans BockGND, Gunnar GraeffeGND, Heikki Juslén |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-761537 |
| DOI: | https://doi.org/10.1515/znb-1975-11-1209 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1975 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/12/29 |
| Tag: | Carbonates; MO Calculations; Photoelectron; Thiocarbonates; X-ray |
| Volume: | 30.1975 |
| Issue: | 11-12 |
| Page Number: | 13 |
| First Page: | 862 |
| Last Page: | 874 |
| HeBIS-PPN: | 517670038 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
