Koordinationschemie reduzierter N-Heterozyklen. Komplexe des Pyrazin-Radikalanions mit Phenylmetallkationen +MPh von Beryllium, Magnesium und Zink
Coordination chemistry of reduced N-heterocycles. Complexes of pyrazine anion radical with phenyl metal cations +MPh of beryllium, magnesium and zinc
- The diphenyls MPh2 (M = Be, Mg, Zn, Cd, Hg) have been reacted with pyrazine (Pz) in tetrahydrofuran. Only the magnesium derivative undergoes electron transfer to yield the 1:1 radical complex [Pz(MgPh)]·. However, in the presence of sodium or potassium persistent 1:2 complexes [Pz(MPh)2]+. are formed with M = Be, Mg, Zn. Use of the higher homologues CdPh2 and HgPh2 leads to reduction to the metals. The 1:2 complexes have been characterized by ESR spectroscopy; metal coupling constants of 9Be, 25Mg and 67Zn could be determined in natural isotopic abundance.
Author: | Wolfgang KaimORCiDGND |
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URN: | urn:nbn:de:hebis:30:3-719562 |
DOI: | https://doi.org/10.1515/znb-1981-0911 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1981 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/09 |
Tag: | ESR Spectra; Electron Transfer; Group II Aryls; Pyrazine; Radical Complexes |
Volume: | 36.1981 |
Issue: | 9 |
Page Number: | 7 |
First Page: | 1110 |
Last Page: | 1116 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |