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Halbstufen-Reduktionspotentiale Bor-substituierter Benzolderivate

Half-wave reduction potentials of boron substituted benzene derivatives

  • The reversible one-electron insertion into mono- and 1,4-di-substituted benzene derivatives is favored by dialkoxyboron and especially by dialkylboron groups. The assumption that it should be the symmetric e2u benzene molecular orbital which is occupied in the resulting radical anions can be supported by comparison of ESR coupling constants.

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Metadaten
Author:Hans BockGND, Werner FußORCiD
URN:urn:nbn:de:hebis:30:3-749206
DOI:https://doi.org/10.1515/znb-1971-0604
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1971
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/07/31
Volume:26
Issue:6
Page Number:4
First Page:525
Last Page:528
HeBIS-PPN:512667101
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0