Photoelektronen-Spektren und Moleküleigenschaften, LXIII. Ionisierungsenergien von Phenyl-Methyl-Tellurid und Vergleich der Effekte von Sauerstoff-, Schwefel-, Selen- und Tellur-Substituenten auf das Benzol-π-System
Photoelectron Spectra and Molecular Properties, LXIII. Ionization Energies of Phenyl Methyl Telluride and Comparison of Effects of Oxygen, Sulphur, Selenium and Tellurium Substituents on the Benzene π System
- The photoelectron spectrum of H5C6-Te-CH3 displays in its low energy region overlapping bands of gas-phase conformers. Depending on the dihedral angle between the plane of the phenyl ring and the tellurium lone pair, the π conjugation amounts to only 0.1 eV and 0.3 eV, respectively. These values are compared to the considerably larger ones found for the analogous phenyl derivatives H5C6-X-CH3 with X = O, S and Se.
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| Author: | Galina Tschmutowa, Hans BockGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-769116 |
| DOI: | https://doi.org/10.1515/znb-1976-1211 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1976 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/09/26 |
| Tag: | Conformers; Photoelectron Spectra; Tellurium Organic Compounds; π Conjugation |
| Volume: | 31 |
| Issue: | 12 |
| Page Number: | 5 |
| First Page: | 1611 |
| Last Page: | 1615 |
| HeBIS-PPN: | 513118063 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
