Zur Reaktion aromatischer Phosphanderivate mit Elektronen, I.
On the reaction of aromatic phosphane derivatives with electrons, I.
- The compounds ;p-Me2P(X)-C6H4-P(X)Me2, X = O, S, Se, NPh undergo one-electron reduction at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixture. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2P-C6H4-PMe2 · with the coordinated groups X.
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| Author: | Wolfgang KaimORCiDGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719437 |
| DOI: | https://doi.org/10.1515/znb-1981-0207 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1981 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | ESR Spectra; Organophosphorus Compounds; Reduction to Radical Anions |
| Volume: | 36.1981 |
| Issue: | 2 |
| Page Number: | 1 |
| First Page: | 150 |
| Last Page: | 156 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
