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Azide und Nitrile cyclischer λ5-Phosphazene

Azides and nitriles of cyclic λ5-phosphazenes

  • The kinetically stable triazatriphosphorinyl and tetraazatetra-phosphorocinyl azides 3 and 4 are prepared from the corresponding chlorides 1, 2 with sodium azide. 3 and 4 react with phosphanes to yield the λ5 -diphosphazenes 5a-d. By the reaction of 1 or 2 with KCN the nitriles 6 and 7 are formed. -The new compounds are characterized on the basis of IR and mass spectra.

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Metadaten
Author:Herbert W. RoeskyORCiDGND, Manfred Banek
URN:urn:nbn:de:hebis:30:3-719346
DOI:https://doi.org/10.1515/znb-1979-0523
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1979
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2024/01/09
Tag:Cycles; Fluoro Compounds
Volume:34.1979
Issue:5
Page Number:3
First Page:752
Last Page:754
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0