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A method for the study of correlated events in time-of-flight mass-spectrometry and its application to fission-fragment induced desorption

  • For experiments on fission-fragment induced desorption the detection of significant correlations between desorbed ions has been reported [1]. In this paper the method for the detection and quantitative description of these correlations will be described. The statistics of the desorption-process leads to equations for mass-line intensities of ion spectra. Using a time-to-amplitude-converter for flight-time measurements these intensities depend on interdependences of different ions desorbed by the same fission-fragment. The equations allow the computation of correlationcoefficients whose interdependence with desorption probabilities of the respective ions can be shown in Venn-diagrams. Results are given and an interpretation is suggested for fission-fragment desorbed thiamine molecular and fragment ions.

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Metadaten
Author:Norbert Fürstenau
URN:urn:nbn:de:hebis:30:3-742257
DOI:https://doi.org/10.1515/zna-1978-0509
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:English
Date of Publication (online):2014/06/02
Year of first Publication:1978
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/06/26
Volume:33
Issue:5
Page Number:8
First Page:563
Last Page:570
HeBIS-PPN:510758746
Institutes:Physik
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0