Elektronentransfer und Ionenpaar-Bildung, 8 [1]. 107,109Ag ENDOR-Kopplungen und Redox-Verhalten des Radikal-Kontaktionenpaares aus Bis(triphenyIphosphino)silber(I)-Kation und 3,5-Di(tert-butyl)-o-benzosemichinon-Anion
Electron transfer and ion pairing, 8 [1]. 107'109Ag ENDOR couplings and redox behaviour of the radical contact ion pair from bis(triphenylphosphino)silver(I) cation and 3,5-di(tert-butyl)-o-benzosemiquinone anion
- For the first time, 107,109Ag ENDOR measurements in solution are reported. In addition, the formation of the known paramagnetic contact ion pair [Ag⊕(PR3)2(R2H2C6O2·⊖] on reduction of 3,5-di(tert-butyl)-o-benzoquinone in THF solution containing soluble silver salts and triphenylphosphine is studied by cyclic voltammetry.
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| Author: | Hans BockGND, Bernhard HierholzerGND, Dieter JaculiGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-669267 |
| DOI: | https://doi.org/10.1515/znb-1988-1006 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1988 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Granting Institution: | Johann Wolfgang Goethe-Universität |
| Release Date: | 2024/01/22 |
| Tag: | Contact Ion Pair [Ag⊕(PR3)2(R2H2C6O2·⊖)]; Cyclic Voltammetry; ENDOR Couplings |
| Volume: | 43.1988 |
| Issue: | 10 |
| Page Number: | 6 |
| First Page: | 1247 |
| Last Page: | 1252 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
