Zur Reaktion von [Cp2TiCl2] und [CpTiCl3] mit E(SiMe3)2 (E = S, Se). Die Kristallstrukturen von [Cp3Ti2S2Cl], [Cp4Ti2S2Cl2], [Cp3Ti2Se2Cl] und [Cp4Ti4Se7O]
Reaction of [Cp2TiCl2] and [CpTiCl3] with E(SiMe3)2 (E = S. Se). The crystal structures of [Cp3Ti2S2Cl], [Cp3Ti2S2Cl2], [Cp3Ti2Se2Cl] and [Cp4Ti4Se7O]
- The reaction of [Cp2TiCl2 ] with E(SiMe3)2 leads to dinuclear Ti complexes. In [Cp3Ti2S2Cl] (1) and [Cp3Ti2Se2Cl] (3) two μ2 -S(Se) ligands bridge the Cp2Ti and CpTiCl units, respectively in contrast to these, [Cp4Ti2S2Cl2] (2) contains a μ2η1-S2 bridge connecting two Cp2TiCl fragments. A similar reaction of [CpTiCl3] with Se(SiMe3)2 leads to the tetranuclear cluster [Cp4Ti4Se7O] (4). 4 consists of a Ti4 -tetrahedron which encloses an oxygen atom.
Download full text files
Additional Services
| Author: | Paul Georg Maué, Dieter FenskeGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-714357 |
| DOI: | https://doi.org/10.1515/znb-1988-1001 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1988 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/18 |
| Tag: | Crystal Structure Dinuclear Ti-S and Ti-Se Complexes; Tetranuclear Ti Cluster; X-Ray |
| Volume: | 43.1988 |
| Issue: | 10 |
| Page Number: | 6 |
| First Page: | 1213 |
| Last Page: | 1218 |
| Note: | Teil von Maué, Paul Georg: Neue Übergangsmetallkomplexe mit Chalkogenliganden. Frankfurt (Main), Univ., Diss., 1988 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
