Zur Reaktion aromatischer Phosphanderivate mit Elektronen, I.
On the reaction of aromatic phosphane derivatives with electrons, I.
- The compounds ;p-Me2P(X)-C6H4-P(X)Me2, X = O, S, Se, NPh undergo one-electron reduction at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixture. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2P-C6H4-PMe2 · with the coordinated groups X.
Author: | Wolfgang KaimORCiDGND |
---|---|
URN: | urn:nbn:de:hebis:30:3-719437 |
DOI: | https://doi.org/10.1515/znb-1981-0207 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1981 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/09 |
Tag: | ESR Spectra; Organophosphorus Compounds; Reduction to Radical Anions |
Volume: | 36.1981 |
Issue: | 2 |
Page Number: | 1 |
First Page: | 150 |
Last Page: | 156 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |