Photoelektronenspektren und Moleküleigenschaften, LXIV. Dimethyldiselenid - ein Beispiel für die Wechselwirkung zwischen benachbarten Elektronenpaaren
Photoelectron Spectra and Molecular Properties, LXIV. Dimethyldiselenide - an Example for the Interaction between Adjacent Electron Pairs
- The well-resolved helium(I) photoelectron spectrum of H3C-Se—Se-CH3 exhibits distinct bands corresponding to 11 of the total 13 valence electron ionizations. The unequivocal assignment is supported by EHMO calculations including spin/orbit coupling. The two selenium lone pair ionizations differ by 0.23 eV; a split observed also for dimethyl disulfide and discussed within a general model for interactions between adjacent lone pairs.
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| Author: | Galina Tschmutowa, Hans BockGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-769099 |
| DOI: | https://doi.org/10.1515/znb-1976-1212 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1976 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/09/26 |
| Tag: | Electron Pair Interaction; Gas Phase Conformation; Photoelectron Spectra; Selenium Organic Compounds |
| Volume: | 31 |
| Issue: | 12 |
| Page Number: | 5 |
| First Page: | 1616 |
| Last Page: | 1620 |
| HeBIS-PPN: | 513117989 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
