Remote and α-thio carbene complexes derived from an oxazolinylsubstituted thiophene
- Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.
Author: | Liliana Dobrzańska, Gerrit R. Julius, Elzet Stander-Grobler, Yolanda Burger, Stefan Dietrich NogaiGND, Stephanie CronjeORCiD, Helgard G. RaubenheimerORCiD |
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URN: | urn:nbn:de:hebis:30:3-799794 |
DOI: | https://doi.org/10.5560/znb.2012-0118 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 2012 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/26 |
Tag: | Carbene Complexes; Chromium; Palladium; Thienylidene Complexes; remote Carbenes |
Volume: | 67.2012 |
Issue: | 6 |
Page Number: | 10 |
First Page: | 509 |
Last Page: | 518 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |