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Röntgenspektroskopische Untersuchung der chemischen Bindung in Oxiden. II

  • The O-K-spectra of α- and γ-Al2O3, β-Ga2O3 and In2O3 were measured with a high-resolution grating spectrograph using the method of electron excitation. The spectra were corrected for the nonlinear response of the photographic emulsions. A shift of the O - K-emission band edge of γ-Al2O3 to lower energy with respect to that of α-Al2O3 and a fine structure within all O -K-bands were observed for the first time. The details of the spectra are discussed in relation to the energy level diagrams, crystal structure, and chemical bond of these oxides.

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Metadaten
Author:Hans-Ulrich ChunGND, Georg Klein
URN:urn:nbn:de:hebis:30:3-742117
DOI:https://doi.org/10.1515/zna-1969-0612
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1969
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/06/22
Volume:24
Issue:6
Page Number:8
First Page:930
Last Page:937
HeBIS-PPN:510577520
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0