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Mikrowellenspektrum, Struktur und interne Rotation von 2,2,2-Trifluor-1,1,1-trichloräthan

  • The microwave spectrum of CF3CCl3 has been investigated in the region from 15 to 40 GHz. A least squares analysis of the rotational constants gave the following structural parameters: dC–C= (1,5394 ± 0,001) A, dC–F= (1,330 ±0,001) A, dC-Cl = (1,7710 ± 0,0009) A, ∢ C—C—F = (109,55 ± 0,25) °, ∢ C—C—Cl= (109,55 ± 0,25) °. The splitting of the torsional satellite may be explained by the theory of KOEHLER and DENNISON.

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Metadaten
Author:Reimer Holm, Michael MitzlaffGND, Hermann HartmannGND
URN:urn:nbn:de:hebis:30:3-740690
DOI:https://doi.org/10.1515/zna-1968-0714
ISSN:1865-7109
Parent Title (German):Zeitschrift für Naturforschung, A
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1968
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/06/23
Volume:23
Issue:7
Page Number:3
First Page:1040
Last Page:1042
HeBIS-PPN:510489346
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0