Darstellung, Eigenschaften, KMR-, IR- und Raman-Spektren von Verbindungen des Typs R-P(Se)F2, R-P(Se)FCl und R-P(Se)Cl2
Preparation, chemical properties, NMR- and vibrational spectra of compounds of the type R-P(Se)F2-, R-P(Se)FCl and R-P(Se)Cl2
- R-P(Se)F2- (R = CH3, C2H5, C3H11, C6H5, N(CH3)2, N(C2H5)2, NHSi(CH3)3) and R-P(Se)FCl-compounds (R = CH3, C2H5) can be prepared by reaction of R-P(Se)Cl2-derivatives with antimony(III)fluoride under reduced pressure. In some cases the oxidation of fluorophophines with elemental selenium is successful. The isolated compounds are colourless volatile liquids which are sensitive to air and moisture. The chemical properties are described. 1H-, 19F-, 31P-NMR-, IR- and Raman-spectroscopic data are given. Main stretching frequencies are discussed by comparison with similar oxygen- and sulphur-compounds.
Author: | Herbert W. RoeskyORCiDGND, Wolfgang KlokerGND |
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URN: | urn:nbn:de:hebis:30:3-761195 |
DOI: | https://doi.org/10.1515/znb-1973-11-1201 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1973 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2023/09/25 |
Tag: | IR-spectra; NMR -spectra; Raman-spectra; Seleniumphosphoryl-compounds |
Volume: | 28 |
Issue: | 11-12 |
Page Number: | 10 |
First Page: | 607 |
Last Page: | 706 |
HeBIS-PPN: | 513115242 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |