Thermodynamische Untersuchungen der Systeme Pyridin/CH3SiCl3 und Pyridin/Cl3CCH3
Thermodynamic Examinations of the Systems Pyridine/CH3SiCl3 and Pyridine/Cl3CCH3
- The isobaric melting and boiling diagrams for the systems: pyridine/methyltrichlorosilane and pyridine/1,1,1-trichloroethane are reproduced. The existence of the congruently melting addition compound CH3SiCl3· (Pyridin)2 could be confirmed. Some measurements of the molar volume of mixtures between pyridine and methyltrichlorosilane and pyridine and 1,1,1-trichloroethane, respectively, are reported. For both systems the molar excess volume and for the system pyridine/methyltrichlorosilane the molar excess enthalpie have been calculated as a function of the mole fractions.
Author: | Michael W. Zenke, Karl Hensen |
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URN: | urn:nbn:de:hebis:30:3-816381 |
DOI: | https://doi.org/10.1515/znb-1993-0815 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1993 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/18 |
Volume: | 48.1993 |
Issue: | 8 |
Page Number: | 6 |
First Page: | 1127 |
Last Page: | 1132 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |