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Substitutionsreaktionen mit Phosphoramiden

Substitution reactions with phosphorus amides

  • By reacting S = PX2NHCH3 or O = PX2NHCH3 (X = F and/or Cl) with S = PF2Br in the presence of triethylamine the following compounds are prepared: S = PCl2NCH3F2P = S, S = PFClNCH3F2P = S, O = PCl2NCH3F2P = S and O = PFClNCH3F2P = S. Also, the infrared, proton NMR, fluorine NMR, phosphorus NMR, and mass spectral data of these compounds are presented and discussed.

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Metadaten
Author:Herbert W. RoeskyORCiDGND, Wolfgang Schaper
URN:urn:nbn:de:hebis:30:3-761090
DOI:https://doi.org/10.1515/znb-1972-1004
ISSN:1865-7117
ISSN:0932-0776
Parent Title (German):Zeitschrift für Naturforschung, B
Publisher:Verlag der Zeitschrift für Naturforschung
Place of publication:Tübingen
Document Type:Article
Language:German
Date of Publication (online):2014/06/02
Year of first Publication:1972
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/09/25
Volume:27
Page Number:4
First Page:1137
Last Page:1140
HeBIS-PPN:513114874
Institutes:Biochemie, Chemie und Pharmazie / Biochemie und Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0