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Mixed-valence compounds as polarizing agents for overhauser dynamic nuclear polarization in solids

  • Herein, we investigate a novel set of polarizing agents—mixed-valence compounds—by theoretical and experimental methods and demonstrate their performance in high-field dynamic nuclear polarization (DNP) NMR experiments in the solid state. Mixed-valence compounds constitute a group of molecules in which molecular mobility persists even in solids. Consequently, such polarizing agents can be used to perform Overhauser-DNP experiments in the solid state, with favorable conditions for dynamic nuclear polarization formation at ultra-high magnetic fields.
Metadaten
Author:Andrei GurinovORCiD, Benedikt Sieland, Andrey KuzhelevORCiD, Hossam ElgabartyORCiDGND, Thomas D. KühneORCiD, Thomas PrisnerORCiD, Jan H. H. ParadiesORCiDGND, Marc BaldusORCiDGND, Konstantin L. IvanovORCiDGND, Svetlana PylaevaORCiDGND
URN:urn:nbn:de:hebis:30:3-725715
DOI:https://doi.org/10.1002/anie.202103215
ISSN:1521-3773
Parent Title (English):Angewandte Chemie : International edition
Publisher:Wiley-VCH
Place of publication:Weinheim
Document Type:Article
Language:English
Date of Publication (online):2021/04/28
Date of first Publication:2021/04/28
Publishing Institution:Universitätsbibliothek Johann Christian Senckenberg
Release Date:2023/04/24
Tag:DNP in solids; Overhauser effect; ab initio calculations; mixed valence compounds; molecular dynamics
Volume:60
Issue:28
Page Number:5
First Page:15371
Last Page:15375
Note:
This work has been supported by iNEXT-Discovery, grant number 871037, funded by the Horizon 2020 program of the European Commission. Open access funding enabled and organized by Projekt DEAL.
HeBIS-PPN:508541832
Institutes:Biochemie, Chemie und Pharmazie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Sammlungen:Universitätspublikationen
Licence (German):License LogoCreative Commons - CC BY - Namensnennung 4.0 International