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Über Additionsreaktionen von zinnorganischen Verbindungen mit N.N′-Bis(pentafluorphenyl)-schwefeldiimid
Addition reactions of tinorganic compounds with N,N′-Bis(pentafluorophenyl)sulfurdiimide
- The reactions of N,N′ -bis(pentafluorophenyl)sulfurdiimide with [(CH3)3Sn]2NCH3, [(CH3)3Sn]3N and [(CH3)3Sn]2NC6F5 yiels the 1:1 adducts 1-3. 1H and 19 F NMR investigations show, that fluorine atoms in the ortho position of the phenyl ring coordinate to the tin atom. This causes an increase of electron density at tin. A similar interpretation is given for the adduct 4 of N,N′-bis(p-chlorophenylsulfonyl)sulfurdiimide and [(CH3)3Sn]2NCH3, where an oxygen atom of the sulfonyl group is bonded to tin.
Author: | Herbert W. RoeskyORCiDGND, Wilfried SchmiederGND, Klaus Ambrosius |
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URN: | urn:nbn:de:hebis:30:3-719315 |
DOI: | https://doi.org/10.1515/znb-1979-0212 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1979 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/09 |
Tag: | Coordination Compounds; Pentafluorophenyl Derivatives; Tin |
Volume: | 34.1979 |
Issue: | 2 |
Page Number: | 3 |
First Page: | 197 |
Last Page: | 199 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |