(4R)-4-(Biphenyl-4-yl)-7-chloro-1,2,3,4-tetrahydroquinoline
- The title compound, C(21)H(18)ClN, was synthesized by an enanti-oselective Brønsted acid-catalysed transfer hydrogenation reaction. The six-membered heterocycle adopts a half-chair conformation. It has the biphenyl residue in an axial position. The two rings of the biphenyl residue are almost coplanar [dihedral angle = 2.65 (9)°]. The crystal packing is stabilized by N-H⋯Cl hydrogen bonds, which connect the mol-ecules into chains running along the a axis.
Author: | Thomas Theissmann, Michael BolteORCiD |
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URN: | urn:nbn:de:hebis:30:3-252997 |
DOI: | https://doi.org/10.1107/S160053681103830X |
ISSN: | 1600-5368 |
Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/22064825 |
Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
Publisher: | Munksgaard |
Place of publication: | Copenhagen |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2011/09/30 |
Date of first Publication: | 2011/09/30 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2012/06/27 |
Volume: | 67 |
Issue: | o2747 |
Page Number: | 10 |
HeBIS-PPN: | 35758810X |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung 3.0 |