Tetraacetonitrilelithium tetraisothiocyanatoborate
- The crystal structure of the title salt, [Li(CH3CN)4][B(NCS)4], is composed of discrete cations and anions. Both the Li and B atoms show a tetrahedral coordination by four equal ligands. The acetonitrile and isothiocyanate ligands are linear. The bond angles at the B atom are close to the ideal tetrahedral value [108.92 (18)–109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)–113.70 (17)°].
| Author: | Jens Michael BreunigGND, Ulrich WietelmannORCiD, Hans-Wolfram LernerORCiDGND, Michael BolteORCiD |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-258632 |
| DOI: | https://doi.org/10.1107/S1600536813009082 |
| ISSN: | 1600-5368 |
| Pubmed Id: | https://pubmed.ncbi.nlm.nih.gov/23723766 |
| Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
| Publisher: | Munksgaard |
| Place of publication: | Copenhagen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2013/04/10 |
| Date of first Publication: | 2013/04/10 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2013/06/08 |
| Volume: | 69 |
| Issue: | m253 |
| Page Number: | 7 |
| Note: | Copyright © Breunig et al. 2013 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| HeBIS-PPN: | 339678046 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung 3.0 |
