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Institute
Active piezoelectric transducers are successfully deployed in recent years for structural health monitoring using guided elastic waves or electro-mechanical impedance (EMI). In both domains, damage detection can be hampered by operational/environmental conditions and low-power constraints. In both domains, processing can be divided into approaches (i) taking into account baselines of the pristine structure as reference, (ii) ingesting an extensive measurement history for clustering to explore anomalies, (iii) incorporating additional information to label a state. The latter approach requires data from complementary sensors, learning from laboratory/field experiments or knowledge from simulations which may be infeasible for complex structures. Semi-supervised approaches are thus gaining popularity: few initial annotations are needed, because labels emerge through clustering and are subsequently used for state classification. In our work, bending and combined bending/torsion studies on rudder stocks are considered regarding EMI-based damage detection in the presence of load. We discuss the underpinnings of our processing. Then, we follow strategy (i) by introducing frequency warping to derive an improved damage indicator (DI). Finally, in a semi-supervised manner, we develop simple rules which even in presence of varying loads need only two frequency points for reliable damage detection. This sparsity-enforcing low-complexity approach is particularly beneficial in energy-aware SHM scenarios.
We compare the microscopic transport models UrQMD, PHSD, PHQMD, and SMASH to make predictions for the upcoming Ag + Ag data at Elab = 1.58A GeV (√sNN = 2.55 GeV) by the HADES collaboration.We study multiplicities, spectra and effective source temperatures of protons, π±,0, K±, the η, Λ+Σ0 and the Ξ− within these models. Despite variations in the detailed
implementation of the dynamics in the different models, the employed transport approaches all show consistent multiplicities of the bulk of investigated hadrons. The main differences are in the Ξ− production, which is treated differently between UrQMD/SMASH on one side employing high mass resonance states with explicit decays to Resonance → Ξ + K + K in contrast to PHSD/PHQMD which account only non-resonant Ξ production channels. A comparison of the spectra, summarized by effective source temperatures, shows that all models provide similar source temperatures around Tsource = 80–95 MeV, and show substantial radial flow on the order of vT = 0.18c − 0.24c even for such a small system.
A hydrogen theta-pinch plasma is diagnosed by two-color interferometry to determine the line density of the free electrons and the hydrogen gas. From the ratio of these line densities, the effective ionization can be calculated. The free electron line density and the effective ionization degree are the most essential quantities for the evaluation of the plasma regarding its applicability as a target in context of plasma ion beam interaction to increase the charge state of the ion beam (plasma stripper). The two-color interferometric diagnostic shows that both line densities exhibit a periodic behavior predefined by the periodic current and at the time the free electron line density reaches a local maximum, the hydrogen line density falls to a local minimum. This occurs, because the plasma axially expands from the coil center by evading the radial compression force of the magnetic field, creating an ionizing wave in the residual gas. The theta-pinch was set up in two versions, with one of them using a cylindrical coil and the other using a spherical coil. For the cylindrical version, the best working point regarding the free electron line density and the effective ionization degree is (1.45 ± 0.04) × 1018 cm−2 and (0.826 ± 0.022) at 20 Pa and 16 kV. In contrast, for the spherical version, lower values of (1.23 ± 0.03) × 1018 cm−2 and (0.699 ± 0.019) at 20 Pa and 18 kV were found. Additionally, a new set-up is proposed for optimizing the plasma target regarding the free electron line density and the effective ionization degree, as well as how to maintain them on a sufficient level for several 10 µs.
Protein structural dynamics can span many orders of magnitude in time. Photoactive yellow protein’s (PYP) reversible photocycle encompasses picosecond isomerization of the light-absorbing chromophore as well as large scale protein backbone motions occurring on a millisecond timescale. Femtosecond-to-millisecond time-resolved mid-infrared spectroscopy is employed here to uncover structural details of photocycle intermediates up to chromophore protonation and the first structural changes leading to the formation of the partially unfolded signaling state pB. The data show that a commonly thought stable transient photocycle intermediate is actually formed after a sequence of several smaller structural changes. We provide residue-specific spectroscopic evidence that protonation of the chromophore on a few hundreds of microseconds timescale is delayed with respect to deprotonation of the nearby E46 residue. That implies that the direct proton donor is not E46 but most likely a water molecule. Such details may assist the ongoing photocycle and protein folding simulation efforts on the complex and wide time-spanning photocycle of the model system PYP.
Over its rather long history, focused electron beam induced deposition (FEBID) has mostly been used as an auxiliary process in passivating surfaces in sample preparation for transmission electron microscopy. This has changed over the last one and a half decades. On the one hand, FEBID has been established as the leading technical approach to lithography mask repair on the industrial scale. On the other hand, FEBID-related technical and methodological developments, FEBID-derived materials, and FEBID-based device fabrication have had a significant impact in various areas of basic and applied research, such as nanomagnetism and superconductivity, plasmonics, and sensing. Despite this dynamic development, the FEBID user base does still form a rather exclusive club of enthusiasts. In this Perspective, our aim is to provide sufficient insight into the basics of FEBID, its potential, as well as its challenges, to scientists working in the broader fields of materials science, nanotechnology, and device development. It is our hope to spark growing interest and even excitement into FEBID which, as we believe, still has to live up to its full potential.
Amide I difference spectroscopy is widely used to investigate protein function and structure changes. In this article, we show that the common approach of assigning features in amide I difference signals to distinct secondary structure elements in many cases may not be justified. Evidence comes from Fourier transform infrared (FTIR) and 2D-IR spectroelectrochemistry of the protein cytochrome c in the amide I range, in combination with computational spectroscopy based on molecular dynamics (MD) simulations. This combination reveals that each secondary structure unit, such as an alpha-helix or a beta-sheet, exhibits broad overlapping contributions, usually spanning a large part of the amide I region, which in the case of difference absorption experiments (such as in FTIR spectroelectrochemistry) may lead to intensity-compensating and even sign-changing contributions. We use cytochrome c as the test case, as this small electron-transferring redox-active protein contains different kinds of secondary structure units. Upon switching its redox-state, the protein exhibits a different charge distribution while largely retaining its structural scaffold. Our theoretical analysis suggests that the change in charge distribution contributes to the spectral changes and that structural changes are small. However, in order to confidently interpret FTIR amide I difference signals in cytochrome c and proteins in general, MD simulations in combination with additional experimental approaches such as isotope labeling, the insertion of infrared labels to selectively probe local structural elements will be required. In case these data are not available, a critical assessment of previous interpretations of protein amide I 1D- and 2D-IR difference spectroscopy data is warranted.
Many samples of current interest in molecular physics and physical chemistry exist in the liquid phase and are vaporized for use in gas cells, diffuse gas targets, or molecular gas jets. For some of these techniques, the large sample consumption is a limiting factor. When rare, expensive molecules such as custom-made chiral molecules or species with isotopic labels are used, wasting them in the exhaust line of the pumps is quite an expensive and inefficient approach. Therefore, we developed a closed-loop recycling system for molecules with vapor pressures below atmospheric pressure. Once filled, only a few valves have to be adjusted, and a cold trap must be moved after each phase of recycling. The recycling efficiency per turn exceeds 95%.
We consider the relativistic hydrodynamics of non-perfect fluids with the goal of determining a formulation that is suited for numerical integration in special-relativistic and general-relativistic scenarios. To this end, we review the various formulations of relativistic second-order dissipative hydrodynamics proposed so far and present in detail a particular formulation that is fully general, causal, and can be cast into a 3+1 flux-conservative form, as the one employed in modern numerical-relativity codes. As an example, we employ a variant of this formulation restricted to a relaxation-type equation for the bulk viscosity in the general-relativistic magnetohydrodynamics code BHAC. After adopting the formulation for a series of standard and non-standard tests in 1+1-dimensional special-relativistic hydrodynamics, we consider a novel general-relativistic scenario, namely, the stationary, spherically symmetric, viscous accretion on to a black hole. The newly developed solution – which can exhibit even considerable deviations from the inviscid counterpart – can be used as a testbed for numerical codes simulating non-perfect fluids on curved backgrounds.
We study the electron-loss-to-continuum (ELC) cusp experimentally and theoretically by comparing the ionization of U89+ projectiles in collisions with N2 and Xe targets, at a beam energy of 75.91 MeV/u. The coincidence measurement between the singly ionized projectile and the energy of the emitted electron is used to compare the shape of the ELC cusp at weak and strong perturbations. A significant energy shift for the centroid of the electron cusp is observed for the heavy target of Xe as compared to the light target of N2. Our results provide a stringent test for fully relativistic calculations of double-differential cross sections performed in the first-order approximation and in the continuum-distorted-wave approach.
The emission of neutron pairs from the neutron-rich N 1⁄4 12 isotones 18C and 20O has been studied by high-energy nucleon knockout from 19N and 21O secondary beams, populating unbound states of the two isotones up to 15 MeV above their two-neutron emission thresholds. The analysis of triple fragment-n-n correlations shows that the decay 19Nð−1pÞ18C* → 16C þ n þ n is clearly dominated by direct pair emission. The two-neutron correlation strength, the largest ever observed, suggests the predominance of a 14C core surrounded by four valence neutrons arranged in strongly correlated pairs. On the other hand, a significant competition of a sequential branch is found in the decay 21Oð−1nÞ20O* → 18O þ n þ n, attributed to its formation through the knockout of a deeply bound neutron that breaks the 16O core and reduces the number of pairs.