Biochemie und Chemie
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- Thermodynamic excess functions (1) (remove)
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A thermodynamic interpretation of the liquidus curves of some methyltrichloro-respectively dimethyldichlorosilane/lutidine-systems is given. Based on certain approximations it was possible to fit thermodynamic functions to the experimental results to obtain the excess datas of binary systems. A comparison between the models of Redlich-Kister, Wilson and the NRTL-formalism for the free excess enthalpy of binary mixtures is given.