Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
- The asymmetric unit of the title compound, [K(C5HF6N2)(H2O)2]n, is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H ... N hydrogen bonds, forming layers in the ab plane. All –CF3 groups show rotational disorder between two orientations each.
Author: | Hien Ngoc Phan, Hans-Wolfram LernerORCiDGND, Michael BolteORCiD |
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URN: | urn:nbn:de:hebis:30-108404 |
DOI: | https://doi.org/10.1107/S1600536810027133 |
Parent Title (English): | Acta crystallographica / Section E, Structure reports online |
Document Type: | Article |
Language: | English |
Year of Completion: | 2010 |
Year of first Publication: | 2010 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2011/06/17 |
Volume: | 66 |
Issue: | m928 |
Note: | Copyright © Phan et al. 2010 This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
Source: | Acta Crystallographica Section E: Structure Reports Online, 66(Pt 8): m928. ; doi: 10.1107/S1600536810027133 |
HeBIS-PPN: | 273256130 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Sammlungen: | Universitätspublikationen |
Licence (German): | Deutsches Urheberrecht |