Untersuchungen zur Charakterisierung des Prochamazulens Matrizin aus Matricaria chamomilla L.
Studies on the Characterization of the Chamazulene Precursor Matricine from Matricaria chamomilla L.
- The relative configuration of the thermolabile chamazulene precursor matricine has been established by NMR spectrometric studies. The NMR spectral data prove to be consistent with the well-known structure of the chamomile component. On the basis of our results the levorotatory natural substance moreover can be specified stereochemically as (−)-(3S*, 3aR*, 4S*, 9R*, 9aS*, 9bS*)-4-acetoxy-2,3,3a,4,5,9,9a,9b-octahydro-9-hydroxy-3,6,9-trimethylazuleno[4,5-b]furan-2-one.
Author: | Elmar FlaskampGND, Gottfried ZimmermannGND, Gerhard NonnenmacherGND, Otto Isaac |
---|---|
URN: | urn:nbn:de:hebis:30:3-719601 |
DOI: | https://doi.org/10.1515/znb-1982-0420 |
ISSN: | 1865-7117 |
ISSN: | 0932-0776 |
Parent Title (German): | Zeitschrift für Naturforschung, B |
Publisher: | Verlag der Zeitschrift für Naturforschung |
Place of publication: | Tübingen |
Document Type: | Article |
Language: | German |
Date of Publication (online): | 2014/06/02 |
Year of first Publication: | 1982 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2024/01/09 |
Tag: | Matricaria chamomilla L;; Matricine; NMR Spectra; Stereochemistry |
Volume: | 37.1982 |
Issue: | 4 |
Page Number: | 4 |
First Page: | 508 |
Last Page: | 511 |
Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
5 Naturwissenschaften und Mathematik / 57 Biowissenschaften; Biologie / 570 Biowissenschaften; Biologie | |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |