Radical ions, 78 [1, 2]. The oxidative desulfuration of organic cyclic polysulfides to disulfide radical cations in AlCl3/H2CCl2 solution
- Organodisulfide radical cations R2S2′⊕ and R2C2S2 ′⊕ can be generated from aliphatic as well as aromatic cyclic polysulfides in AlCl3/H2CCl2 solutions and characterized by their ESR spectra. Examples presented are the oxidations of 1,2,3-trithiolanes to 1.2-dithiolane radical cations, in which energetically favored planarized 3 electron/2 center bonds are formed.
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| Author: | Hans BockGND, Bertrand Leo Chenard, Peter RittmeyerGND, Udo C. SteinGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-714311 |
| DOI: | https://doi.org/10.1515/znb-1988-0121 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | English |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1988 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/26 |
| Tag: | Cyclic Organosulfides; ESR Spectra; One-Electron Oxidation; Structural and Conformational Changes |
| Volume: | 43.1988 |
| Issue: | 1 |
| Page Number: | 8 |
| First Page: | 117 |
| Last Page: | 124 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
