Untersuchung der Ion-Molekül-Reaktionen des Thiothionylfluorids mit Hilfe der Ionen-Cyclotronresonanz-Spektrometrie
Investigation Of Ion-Molecule Reactions Of Thiothionylfluorid By Ion Cyclotron Resonance Spectrometry
- The ion-molecule reactions of thiothionylfluoride have been studied by ion cyclotron resonance spectrometry. The major secondary ions are S2F3+ , S3F+ , and S3F2+. In a consecutive reaction of S3F2+ the tertiary ion S4F2+ is formed. The rate constant of the IMR with the greatest yield S2F2+ + SSF2 → S3F2+ + SF was estimated to k = 2 · 10-9 cm 3 molecule -1 sec -1 . The results were compared with the mass spectrum of thiothionylfluoride. They permit conclusions on chemical reactions of lower sulphurfluorides.
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| Author: | Karl-Peter Wanczek, Karl-Heinz LebertGND, Hermann HartmannGND |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-740395 |
| DOI: | https://doi.org/10.1515/zna-1972-0123 |
| ISSN: | 1865-7109 |
| Parent Title (German): | Zeitschrift für Naturforschung, A |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1972 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2023/06/26 |
| Volume: | 27 |
| Issue: | 1 |
| Page Number: | 4 |
| First Page: | 155 |
| Last Page: | 158 |
| HeBIS-PPN: | 51048784X |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
