Über Additionsreaktionen von zinnorganischen Verbindungen mit N.N′-Bis(pentafluorphenyl)-schwefeldiimid
Addition reactions of tinorganic compounds with N,N′-Bis(pentafluorophenyl)sulfurdiimide
- The reactions of N,N′ -bis(pentafluorophenyl)sulfurdiimide with [(CH3)3Sn]2NCH3, [(CH3)3Sn]3N and [(CH3)3Sn]2NC6F5 yiels the 1:1 adducts 1-3. 1H and 19 F NMR investigations show, that fluorine atoms in the ortho position of the phenyl ring coordinate to the tin atom. This causes an increase of electron density at tin. A similar interpretation is given for the adduct 4 of N,N′-bis(p-chlorophenylsulfonyl)sulfurdiimide and [(CH3)3Sn]2NCH3, where an oxygen atom of the sulfonyl group is bonded to tin.
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| Author: | Herbert W. RoeskyORCiDGND, Wilfried SchmiederGND, Klaus Ambrosius |
|---|---|
| URN: | urn:nbn:de:hebis:30:3-719315 |
| DOI: | https://doi.org/10.1515/znb-1979-0212 |
| ISSN: | 1865-7117 |
| ISSN: | 0932-0776 |
| Parent Title (German): | Zeitschrift für Naturforschung, B |
| Publisher: | Verlag der Zeitschrift für Naturforschung |
| Place of publication: | Tübingen |
| Document Type: | Article |
| Language: | German |
| Date of Publication (online): | 2014/06/02 |
| Year of first Publication: | 1979 |
| Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
| Release Date: | 2024/01/09 |
| Tag: | Coordination Compounds; Pentafluorophenyl Derivatives; Tin |
| Volume: | 34.1979 |
| Issue: | 2 |
| Page Number: | 3 |
| First Page: | 197 |
| Last Page: | 199 |
| Institutes: | Biochemie, Chemie und Pharmazie / Biochemie und Chemie |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Sammlungen: | Universitätspublikationen |
| Licence (German): |  Creative Commons - Namensnennung-Nicht kommerziell-Keine Bearbeitung 3.0 |
