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High-pressure/high-temperature synthesis of the new boron-rich terbium hydroxyborate Tb3B12O19(OH)7
- Monoclinic Tb3B12O19(OH)7 was obtained by multianvil high-pressure/high-temperature syntheses at 6 GPa and 650 °C. The crystal structure was investigated by single-crystal X-ray diffraction methods and space group C2 (no. 5) with the unit cell parameters a = 24.2299(5) Å, b = 4.4667(1) Å, c = 7.0964(2) Å, β = 94.58(1)°, and two formula units per cell were revealed. Powder X-ray diffraction, infrared spectroscopy and the investigation of its second harmonic generation properties support the proposed structural model.
Author: | Tobias A. TeichtmeisterORCiD, Lkhamsuren BayarjargalORCiDGND, Gunter HeymannORCiDGND, Hubert HuppertzORCiD |
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URN: | urn:nbn:de:hebis:30:3-796896 |
DOI: | https://doi.org/10.1016/j.solidstatesciences.2023.107373 |
ISSN: | 1293-2558 |
Parent Title (English): | Solid state sciences |
Publisher: | Elsevier |
Place of publication: | Amsterdam |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2023/11/21 |
Date of first Publication: | 2023/11/16 |
Publishing Institution: | Universitätsbibliothek Johann Christian Senckenberg |
Release Date: | 2023/11/22 |
Tag: | Borate; Crystal structure; High-pressure; Solid-state chemistry; Terbium |
Volume: | 146 |
Issue: | 107373 |
Article Number: | 107373 |
Page Number: | 7 |
HeBIS-PPN: | 515554758 |
Institutes: | Geowissenschaften / Geographie / Geowissenschaften |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
5 Naturwissenschaften und Mathematik / 55 Geowissenschaften, Geologie / 550 Geowissenschaften | |
Sammlungen: | Universitätspublikationen |
Licence (German): | Creative Commons - CC BY-NC-ND - Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International |